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Preparation and Characterization of Chitosan/Polyvinyl Alcohol Blends-A Rheological Study
Esam A. El-Hefian
,1 Mohamed Mahmoud Nasef,2 and Abdul Hamid Yahaya11Department of Chemistry, Faculty of Science, University of Malaya, 50603 Kuala Lumpur, Malaysia
2Chemical Engineering Department, Faculty of Chemical and Natural Resources Engineering, Universiti Teknologi Malaysia, 81310 UTM Skudai, Johor, Malaysia
Abstract
Blends of chitosan (CS) and polyvinyl alcohol (PVA) of different proportions (considering chitosan as the main component) were prepared. The rheological properties of the obtained blend solutions such as the shearing viscosity and the shear stress were investigated as a function of shear rate under various temperatures, shearing times and solution storage times using a digital viscometer. The CS/PVA solutions showed a Newtonian behavior at temperatures in the range of 40-55 °C regardless of the blend composition. This was accompanied by a general decrease in the viscosity with increasing PVA content in the blend. The heat-dependant viscosity changes of the blend solutions were found to follow Arrhenius equation. The shearing time was found to have no significant effect on the shearing viscosity of all blended solutions. However, the variation of solution storage period was found to have a mixed effect when time was extended to 3 weeks.
Copyright
Copyright © 2010 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
