Journal of Chemistry

Journal of Chemistry / 2010 / Article

Open Access

Volume 7 |Article ID 384948 |

Darfizzi Derawi, Jumat Salimon, "Optimization on Epoxidation of Palm Olein by Using Performic Acid", Journal of Chemistry, vol. 7, Article ID 384948, 9 pages, 2010.

Optimization on Epoxidation of Palm Olein by Using Performic Acid

Received06 Dec 2009
Accepted02 Feb 2010


The epoxidation process of palm olein (POo) was carried out by using in situ generated performic acid (HCOOOH) to produce epoxidized palm olein (EPO). HCOOOH was produced by mixing of formic acid (HCOOH) as oxygen carrier and hydrogen peroxide (H2O2) as oxygen donor in various ratio of POo: HCOOH: H2O2. The effect of HCOOH and H2O2 concentration, temperature, stirring effect and reaction time were studied. The presence of oxirane ring of EPO was characterised by fourier transformation infra-red (FTIR), proton and carbon nuclear magnetic resonance (1H-NMR and (13C-NMR) spectra. The results showed that an optimum oxirane oxygen content (OOC) value was obtained by using mol ratio of 1: 5: 2 at 150 minutes.

Copyright © 2010 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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