Journal of Chemistry

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Volume 7 |Article ID 782913 | 4 pages | https://doi.org/10.1155/2010/782913

A Convenient Access to Biquinoline Carbaldehydes using Nickel-Phosphine Complex-Mediated Homocoupling of Haloquinoline Carbaldehydes in One-Pot Reaction

Ahmed Benameur,1 Taoues Boumoud,1 Boudjemaa Boumoud,1 and Salah Rhouati1

1Laboratoire des Produits Naturels d’origine Végétale et de Synthèse, Organique., Département de Chimie., Faculté des Sciences, Université Mentouri de Constantine 25000 Constantine, Algeria

Received10 Oct 2009
Revised10 Dec 2009
Accepted04 Feb 2010

Abstract

The homocoupling of 2-chloro-carbaldehyde derivatives gave the corresponding 2,2’-biquinolines by using the in situ generated reactive reagent Ni[(PPh3)]4. Several new 2-chloro-3-(1.3 dioxalan-2yl) quinoline derivatives are synthesized and structurally characterized. The overall structures of biquinoline derivatives are not planar.

Copyright © 2010 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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