Journal of Chemistry

Journal of Chemistry / 2011 / Article

Open Access

Volume 8 |Article ID 572603 | https://doi.org/10.1155/2011/572603

N. M. I. Alhaji, S. Sofiya Lawrence Mary, "Kinetics and Mechanism of Oxidation of Glutamic Acid by N-Bromophthalimide in Aqueous Acidic Medium", Journal of Chemistry, vol. 8, Article ID 572603, 6 pages, 2011. https://doi.org/10.1155/2011/572603

Kinetics and Mechanism of Oxidation of Glutamic Acid by N-Bromophthalimide in Aqueous Acidic Medium

Received20 Apr 2011
Accepted25 Jun 2011

Abstract

The kinetics of oxidation of glutamic acid (Glu) with N-bromophthalimide (NBP) was studied in perchloric acid medium at 30 °C by potentiometric method. The reaction is first order each in NBP and glutamic acid and is negative fractional order in [H+]. Addition of KBr or the reaction product, phthalimide had no effect on the rate. Similarly variation of ionic strength of the medium did not affect the rate of the reaction. Also the rate increased with decrease in dielectric constant of the reaction medium. The thermodynamic parameters were computed from Arrhenius and Eyring plots. A suitable mechanism consistent with the kinetic results has been proposed.

Copyright © 2011 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


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