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E-Journal of Chemistry
Volume 8 (2011), Issue 1, Pages 288-292
http://dx.doi.org/10.1155/2011/590923

Microwave Promoted Regeneration of Carbonyl Compounds from Oximes Using N, N-Dichloro Poly(Styrene-co-divinylbenzene)Sulphonamide Resin

A.G. Beldar and Mamta Sharma

Synthetic Chemistry Division, Defence R & D Establishment, Jhansi Road, Gwalior-474002, M.P., India

Received 10 May 2010; Accepted 20 July 2010

Copyright © 2011 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

An efficient, economically viable and operationally simple method was developed for deoximation of oximes (of ketones and aldehydes) to their corresponding carbonyl compounds using polymer beads of N, N-dichloro poly(styrene-co-divinylbenzene)sulphonamide resin. Polymeric reagent offered speedy conversion and substantial yields of products under mild condition and is recyclable. Deoximation was monitored by the use of 13C NMR.