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E-Journal of Chemistry
Volume 8, Issue 1, Pages 421-426
http://dx.doi.org/10.1155/2011/650764

Synthesis and Structural Studies of Cr(III), Mn(II) and Fe(III) Complexes of N(2-Benzimidazolyl)acetylacetohydrazone

G. H. Anuradha1 and A. V. Chandra Pal2

1Department of Chemistry, R.B.V.R.R Women's College, Hyderabad-500027, India
2Department of Chemistry, Osmania University, Hyderabad-500007, India

Received 9 February 2010; Revised 25 June 2010; Accepted 17 July 2010

Copyright © 2011 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

The ligand N(2-benzimidazolyl)acetylacetohydrazone (BAAH) have been synthesized and characterized. Coordination complexes of Cr(III), Mn(II) and Fe(III) have been synthesized with the ligand BAAH. These complexes were characterized on the basis of analytical, conductance, thermal, magnetic data and infrared and electronic spectral data. The ligand BAAH is behaving as a neutral tridentate NNO donar employing two azomethine nitrogens (ring and side chain) and carbonyl oxygen. The ligand and it's metal complexes were tested for anti microbial activity on the gram positive S. Aureus, E. coli and Proteus.