Journal of Chemistry

Journal of Chemistry / 2012 / Article

Open Access

Volume 9 |Article ID 205123 | 7 pages | https://doi.org/10.1155/2012/205123

Syntheses and Spectroscopic Studies on Macrocyclic Complexes of Dioxomolybdenum(VI) with Furil as Precursor

Received20 Jul 2011
Accepted21 Sep 2011

Abstract

Due to their biological relevance, molybdenum catalyzed oxygen transfer reactions have great interest. With this view, some dioxomolybdenum(VI) complexes with general formula [MoO2(mac)](acac)2, (where mac = tetraazamacrocyclic ligands derived from condensation of furil with 1,2-ethanediamine or 1,3-propanediamine and their reaction with β-diketones) have been synthesized using dioxometal ion as kinetic template. The prepared complexes have been characterized by electrical conductance, elemental analyses, infrared and electronic data. All the dioxomoly-bdenum(VI) complexes have octahedral geometry with six coordination.

Copyright © 2012 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


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