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E-Journal of Chemistry
Volume 9, Issue 1, Pages 308-312
http://dx.doi.org/10.1155/2012/239245

Gadolinium(III) Ion-Selective Electrode Based on 3-Methyl-1H-1,2,4-triazole-5-thiol

Hassan Ali Zamani1 and Hossein Behmadi2

1Department of Applied Chemistry, Quchan Branch, Islamic Azad University, Quchan, Iran
2Department of Chemistry, Mashhad Branch, Islamic Azad University, Mashhad, Iran

Received 16 May 2011; Accepted 15 July 2011

Copyright © 2012 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

The 3-methyl-1H-1,2,4-triazole-5-thiol (MTH) was used as a suitable ionophore for fabrication of a new gadolinium(III) ion selective potentiometric sensor. Nitrobenzene (NB) was used as plasticizing solvent mediator and sodium tetraphenyl borate (NaTPB) as an anion excluder. It displays a Nernstian response (19.8± 0.4 mV/decade) in the concentration range of 1.0×10-7 to 1.0×10-2 M with the detection limit of 7.3×10-8 M. The sensor has a very short response time (<10s) and can be used the pH range of 2.9-8.4. electrode was successfully applied as an indicator for gadolinium determination in titration with EDTA.