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Theoritical Evaluation of Ultrasonic Velocities in Binary Liquid Mixtures of N-Methyl-2-pyrrolidone at Different Temperatures with Some Cyclic Compounds
K. Rayapa Reddy,1 D. Bala Karuna Kumar,1 C. Rambabu
,1 and G. Srinivasa Rao21Department of Chemistry, Acharya Nagarjuna University PG Centre, Nuzvid, Andhra Pradesh, India
2Department of Physics, Andhra Loyola College, Vijayawada, Andhra Pradesh, India
Abstract
Ultrasonic velocities and densities of the binary liquid mixtures of N-methyl-2-Pyrrolidone (NMP) with Cyclohexylamine (CHA), Cyclohexanol (CHOL) and Cyclohexene(CHE) at a temperature range of 303.15 to 318.15 K over the entire composition range were measured. The theoretical values of ultrasonic velocity were evaluated using the Nomoto's relation(UNR), Impedence relation(UIR), Ideal mixing relation(UIMR), Jungie's relation(UJR) and Rao's specific velocity relation(UR).The molecular interaction parameter (α) was computed by using the experimental and theoretical ultrasonic velocity values. The variation of interaction parameter with the composition of the mixture has been discussed in terms of molecular interactions.
Copyright
Copyright © 2012 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
