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E-Journal of Chemistry
Volume 9, Issue 2, Pages 553-562
http://dx.doi.org/10.1155/2012/571521

Theoritical Evaluation of Ultrasonic Velocities in Binary Liquid Mixtures of N-Methyl-2-pyrrolidone at Different Temperatures with Some Cyclic Compounds

1Department of Chemistry, Acharya Nagarjuna University PG Centre, Nuzvid, Andhra Pradesh, India
2Department of Physics, Andhra Loyola College, Vijayawada, Andhra Pradesh, India

Received 13 July 2011; Accepted 20 September 2011

Copyright © 2012 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

Ultrasonic velocities and densities of the binary liquid mixtures of N-methyl-2-Pyrrolidone (NMP) with Cyclohexylamine (CHA), Cyclohexanol (CHOL) and Cyclohexene(CHE) at a temperature range of 303.15 to 318.15 K over the entire composition range were measured. The theoretical values of ultrasonic velocity were evaluated using the Nomoto's relation(UNR), Impedence relation(UIR), Ideal mixing relation(UIMR), Jungie's relation(UJR) and Rao's specific velocity relation(UR).The molecular interaction parameter (α) was computed by using the experimental and theoretical ultrasonic velocity values. The variation of interaction parameter with the composition of the mixture has been discussed in terms of molecular interactions.