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E-Journal of Chemistry
Volume 9, Issue 3, Pages 1113-1121
http://dx.doi.org/10.1155/2012/585827

Synthesis, Spectral and Antimicrobial Studies of Some Co(II), Ni(II) and Cu(II) Complexes Containing 2-Thiophenecarboxaldehyde Moiety

Synthetic Inorganic & Coordination Chemistry Laboratories, Department of Chemistry, Dr. H. S. Gour Central University, Sagar (M.P.)-470 003, India

Received 26 September 2011; Accepted 8 November 2011

Copyright © 2012 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

Some new Schiff base metal complexes of Co(II), Ni(II) and Cu(II) derived from 3-chloro-4-fluoroaniline (HL1) and 4-fluoroaniline (HL2) with 2-thiophenecarboxaldehyde have been synthesized and characterized by elemental analysis, FT-IR, FAB-mass, molar conductance, electronic spectra, ESR and magnetic susceptibility. The complexes exhibit coordination number 4 or 6. The complexes are colored and stable in air. Analytical data revealed that all the complexes exhibited 1:2 (metal: ligand) ratio. FAB-mass data show degradation pattern of the complexes. The Schiff base and metal complexes show a good activity against the bacteria; B. subtilis, E. coli and S. aureus and fungi A. niger, A. flavus and C. albicans. The antimicrobial results also indicate that the metal complexes are better antimicrobial agents as compared to the Schiff bases.