Table of Contents Author Guidelines Submit a Manuscript
E-Journal of Chemistry
Volume 9, Issue 2, Pages 869-874
http://dx.doi.org/10.1155/2012/623581

Ion-Conducting Polymer Electrolyte Based on Poly (Ethylene Glycol) Complexed with Mg(CH3COO)2 Application as an Electrochemical Cell

Solid State Ionics Research Laboratory, Department of Physics, Dr. Hari Singh Gour University, Sagar, Madhya Pradesh 470003, India

Received 26 July 2011; Accepted 5 September 2011

Copyright © 2012 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

A new Mg2+ -ion conducting polymer electrolyte based on Poly (ethylene glycol) complexed with Mg(CH3COO)2 has been prepared using solution-cast technique. DSC, Composition-dependent conductivity at different temperatures, dielectric studies, and transference number measurements have been performed to characterize the polymer electrolytes. The DSC measurements show decrease in melting point with increase in salt concentration. Out of five different compositions studied, the 85PEG: 15Mg(CH3COO)2 polymer-salt complex showed the highest conductivity with σ = 1.07 x 10-6 S/cm at room temperature (30°C). The transport number measurements have shown that the electrolyte is an ionic conductor. Using the electrolyte, an electrochemical cell with the configuration Mg/(PEG+Mg(CH3 COO)2)/(I2 +C+electrolyte) has been fabricated and its discharge characteristics studied.