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E-Journal of Chemistry
Volume 9, Issue 2, Pages 593-597
http://dx.doi.org/10.1155/2012/646397

Experiences during Synthesis of a Dinucleating Spacer Incorporating 2-Chloropyridine Units Through Sandmayer Reaction

1Coordination Chemistry Research Lab, Department of Chemistry, Govt. Model Science College Jabalpur (MP) 482001, India
2Department of Engineering Chemistry, ITM University, Gwalior, MP, India
3University of Louisiana at Lafayette, LA, 70504, USA

Received 17 March 2011; Revised 28 May 2011; Accepted 21 December 2011

Copyright © 2012 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

A bimetallic cuprous complex was accidentally reported, during synthesis of a dinucleating spacer incorporating two 2-chloropyridine units through Sandmayer reaction. The product was characterized by elemental analysis, FAB-Mass, FT-IR, UV, magnetic susceptibility and 1H-NMR spectroscopic method. A possible mechanism is also proposed.