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E-Journal of Chemistry
Volume 9 (2012), Issue 3, Pages 1342-1346

Synthesis and Characterization of Dodecylbenzene Sulfonic Acid doped Tetraaniline via Emulsion Polymerization

Department of Inorganic and Analytical Chemistry, Andhra University, Visakhapatnam -530003, India

Received 6 July 2011; Accepted 20 September 2011

Copyright © 2012 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


In this work, we report preparation and characterization of dodecylbenzene sulfonic acid (DBSA) doped tetraaniline via micelles assisted method using ammonium per sulphate (APS) as an oxidant. Here, DBSA act as dopant as well as template for tetraaniline nanostructures. The synthesized DBSA doped tetraaniline have been well characterized by X-ray diffraction patterns, Fourier transform infrared spectroscopy, UV-Visible spectroscopy, Scanning electron microscopy and thermogravimetry. The morphologies of tetraaniline were found to be dependent on molar ratios of N-phenyl-1, 4-phenylenediamine to DBSA. The spectroscopic data indicated that DBSA doped tetraaniline. Thermogravimetry studies revealed that the DBSA doping improved the thermal stability of tetraaniline.