Journal of Chemistry

Journal of Chemistry / 2012 / Article

Open Access

Volume 9 |Article ID 950625 | https://doi.org/10.1155/2012/950625

S. D. Deosarkar, A. L. Puyad, S. A. Chavan, "Stability Constants of Some Biologically Important Pyrazoles and Their Ni2+ Complexes in Different Dielectric Constant of Medium", Journal of Chemistry, vol. 9, Article ID 950625, 5 pages, 2012. https://doi.org/10.1155/2012/950625

Stability Constants of Some Biologically Important Pyrazoles and Their Ni2+ Complexes in Different Dielectric Constant of Medium

Received10 Jul 2011
Accepted20 Sep 2011

Abstract

The proton-ligand stability constants of some biologically important new pyrazoles and formation constants of their complexes with Ni(II) were determined at 0.1 mol dm-3 ionic strength and at 303.15 K in different dielectric constant of dioxane-water mixture by potentiometric method. The Calvin-Bjerrum's pH-titration technique as used by Irving and Rossotti was used for determination of stability constants. The results enabled to study the electrostatic forces of attraction between metal ion and ligand with changes in dielectric constant of the medium.

Copyright © 2012 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


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