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E-Journal of Chemistry
Volume 9 (2012), Issue 1, Pages 277-281
http://dx.doi.org/10.1155/2012/985041

Pyridinedicarboxylic Acid Derivatives of Dichlorobis(cyclopentadienyl)titanium(IV)

Satish C. Dixit1 and Rohit K. Singh2

1Deptt. of Chemistry, D.B.S.(P.G.) College, Kanpur-208006, India
2Deptt. of Chemistry, Pt. J.L.N. College, Banda(U.P.), India

Received 19 April 2011; Accepted 2 July 2011

Copyright © 2012 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

Reactions of dichlorobis(cyclopentadienyl)titanium(IV) with pyridine dicarboxylic acids viz. quinolinic acid (QAH2), 2,4-pyridine dicarboxylic acid (PAH2), isocinchomeronic acid (IAH2), cinchomeronic acid (CAH2) and dinicotinic acid (DAH2) were carried out in different stoichiometric ratios. Complexes of the type Cp2Ti(QAH)Cl, Cp2Ti(QAH)2, Cp2Ti(PAH)Cl, Cp2Ti(PAH)2, Cp2Ti(IAH)Cl, Cp2Ti(IAH)2, Cp2Ti(CAH)Cl, Cp2Ti(CAH)2, Cp2Ti(DAH)Cl and Cp2Ti(DAH)2 were obtained. These new complexes were characterized on the basis of their elemental analyses, electrical conductance, magnetic moment and spectral data.