Research Article
Synthesis and Spectroscopic Studies of Axially Ligated Zn(II)5,10,15,20-meso-tetra(p-chlorophenyl)porphyrin with Oxygen and Nitrogen Donors
Table 6
Mass data for X-ZnII-t(p-Cl)PP (X = phenolates and pyridinates as axial ligand).
| | Compound | Formula | m/z ratio | | Observed | Calculated |
| | phO-Zn-t(p-Cl)PP [(C6H5O)Zn(C44N24N4Cl4)] | C50H29N4Cl4ZnO1 | 911.6 | 911.18 | | p-NH2phO-Zn-t(p-Cl)PP [(C6H7NO)Zn(C44N24N4Cl4)] | C50H31N5Cl4ZnO1 | 926.6 | 927.8 | | p-NO2phO-Zn-t(p-Cl)PP [(C6H5NO3)Zn(C44N24N4Cl4)] | C50H29N5Cl4ZnO3 | 956.11 | 956.19 | | 2,4-Cl2phO-Zn-t(p-Cl)PP [(C6H4Cl2O)Zn(C44N24N4Cl4)] | C50H27N4Cl6ZnO1 | 980.2 | 980.8 | | p-OCH3phO-Zn-t(p-Cl)PP [(C7H8O2)Zn(C44N24N4Cl4)] | C51H31N4Cl4ZnO2 | 941.3 | 941.22 | | o-NH2py-Zn-t(p-Cl)PP [(C5H6N2)Zn(C44N24N4Cl4)] | C49H30N6Cl4Zn | 911.4 | 912.08 | | p-CH3py-Zn-t(p-Cl)PP [(C6H7N)Zn(C44N24N4Cl4)] | C50H31N5Cl4Zn | 911.2 | 911.6 |
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