Evaluation of Electronic Effects in the Solvolyses of <i>p</i>-Methylphenyl and <i>p</i>-Chlorophenyl Chlorothionoformate Esters

<div class="floats-full-page floats-full-page-figure"><h2>Figure 5</h2><div class="floats-full-page-caption"><table>The plot of log <svg height="14.7125" id="M147" style="vertical-align:-3.2316pt" version="1.1" viewbox="0 0 37.450001 14.7125" width="37.450001" xmlns="http://www.w3.org/2000/svg">
<g transform="matrix(1.25,0,0,-1.25,0,14.7125)">
<g transform="translate(72,-60.23)">
<text transform="matrix(1,0,0,-1,-71.95,63.5)">
<tspan style="font-size: 12.50px; " x="0" y="0">(</tspan>
<tspan style="font-size: 12.50px; " x="4.1634989" y="0">𝑘</tspan>
<tspan style="font-size: 12.50px; " x="10.940125" y="0">/</tspan>
<tspan style="font-size: 12.50px; " x="14.415959" y="0">𝑘</tspan>
</text>
<text transform="matrix(1,0,0,-1,-50.76,60.37)">
<tspan style="font-size: 8.75px; " x="0" y="0">𝑜</tspan>
</text>
<text transform="matrix(1,0,0,-1,-46.25,63.5)">
<tspan style="font-size: 12.50px; " x="0" y="0">)</tspan>
</text>
</g>
</g>
</svg> for 4-chlorophenyl chlorothionoformate (<b>7</b>) against 1.79 <svg height="14.2375" id="M148" style="vertical-align:-3.13504pt" version="1.1" viewbox="0 0 21.8125 14.2375" width="21.8125" xmlns="http://www.w3.org/2000/svg">
<g transform="matrix(1.25,0,0,-1.25,0,14.2375)">
<g transform="translate(72,-60.61)">
<text transform="matrix(1,0,0,-1,-71.95,63.79)">
<tspan style="font-size: 12.50px; " x="0" y="0">𝑁</tspan>
</text>
<text transform="matrix(1,0,0,-1,-61.31,60.66)">
<tspan style="font-size: 8.75px; " x="0" y="0">𝑇</tspan>
</text>
</g>
</g>
</svg> + 0.45 <svg height="14.3875" id="M149" style="vertical-align:-3.25792pt" version="1.1" viewbox="0 0 19.450001 14.3875" width="19.450001" xmlns="http://www.w3.org/2000/svg">
<g transform="matrix(1.25,0,0,-1.25,0,14.3875)">
<g transform="translate(72,-60.49)">
<text transform="matrix(1,0,0,-1,-71.95,63.79)">
<tspan style="font-size: 12.50px; " x="0" y="0">𝑌</tspan>
</text>
<text transform="matrix(1,0,0,-1,-65.26,60.66)">
<tspan style="font-size: 8.75px; " x="0" y="0">C</tspan>
<tspan style="font-size: 8.75px; " x="5.837584" y="0">l</tspan>
</text>
</g>
</g>
</svg> in the nineteen pure and binary solvents studied. The points for TFE-H<sub>2</sub>O and HFIP-H<sub>2</sub>O are not included in the correlation. They are added to show the extent of their deviation from the correlation.</table></div><div class="floats-full-page-content"><table class="table-group" width="800px"><tr class="fig-image"><td><img alt="248534.fig.005" src="https://static-01.hindawi.com/articles/jchem/volume-2013/248534/figures/248534.fig.005.jpg" /></td></tr></table></div></div>

Figure 5 | Evaluation of Electronic Effects in the Solvolyses of <i>p</i>-Methylphenyl and <i>p</i>-Chlorophenyl Chlorothionoformate Esters

title

Figure 5: Evaluation of Electronic Effects in the Solvolyses of <i>p</i>-Methylphenyl and <i>p</i>-Chlorophenyl Chlorothionoformate Esters

description

Figure 5 | Evaluation of Electronic Effects in the Solvolyses of p-Methylphenyl and p-Chlorophenyl Chlorothionoformate Esters

Figure 5

About this journal

<p><em>Journal of Chemistry </em>publishes original research articles as well as review articles on all aspects of fundamental and applied chemistry, including biological, environmental, forensic, inorganic, organic, physical and theoretical.</p>


Journal profile

Meet the editorial board

<p><em>Journal of Chemistry</em> maintains an Editorial Board of practicing researchers from around the world, to ensure manuscripts are handled by editors who are experts in the field of study.</p>


Editor spotlight

Submit to Special Issue

We currently have a number of Special Issues open for submission. Special Issues highlight emerging areas of research within a field, or provide a venue for a deeper investigation into an existing research area.