Synthesis, Characterization, and Physicochemical Studies of Mixed Ligand Complexes of Inner Transition Metals with Lansoprazole and Cytosine

<table class="table-group" id="tab6"><tr><td><table class="table"><tr><td class="thead-hr" colspan="3"><hr/></td></tr><tr class="thead"><td align="left">Metal complex</td><td align="center">Structure</td><td align="center">Spectral mass</td></tr><tr><td class="thead-hr" colspan="3"><hr/></td></tr><tr><td align="left"><svg height="14.85" id="M74" style="vertical-align:-2.22495pt" version="1.1" viewbox="0 0 5.9875002 14.85" width="5.9875002" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.017,-0,0,-.017,.062,12.012)"><path d="M290 -163h-170v866h170v-28q-79 -7 -94 -19.5t-15 -72.5v-627q0 -59 14.5 -71.5t94.5 -19.5v-28z" id="x5B"></path></g>
</svg>Th<svg height="5.4499998" id="M75" style="vertical-align:-0.0pt" version="1.1" viewbox="0 0 4 5.4499998" width="4" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.017,-0,0,-.017,.062,5.388)"><path d="M170 255q0 -25 -16 -41t-40 -16t-40 16t-16 41t16 41.5t40 16.5t40 -16.5t16 -41.5z" id="x22C5"></path></g>
</svg>Lanso<svg height="5.4499998" id="M76" style="vertical-align:-0.0pt" version="1.1" viewbox="0 0 4 5.4499998" width="4" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.017,-0,0,-.017,.062,5.388)"><path d="M170 255q0 -25 -16 -41t-40 -16t-40 16t-16 41t16 41.5t40 16.5t40 -16.5t16 -41.5z" id="x22C5"></path></g>
</svg>Cyto<svg height="5.4499998" id="M77" style="vertical-align:-0.0pt" version="1.1" viewbox="0 0 4 5.4499998" width="4" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.017,-0,0,-.017,.062,5.388)"><path d="M170 255q0 -25 -16 -41t-40 -16t-40 16t-16 41t16 41.5t40 16.5t40 -16.5t16 -41.5z" id="x22C5"></path></g>
</svg>4H<sub>2</sub>O]NO<sub>3</sub>·<i>x</i>H<sub>2</sub>O</td><td align="center">1 : 1 : 1 : 4H<sub>2</sub>O</td><td align="center">793</td></tr><tr><td align="left"><svg height="14.85" id="M78" style="vertical-align:-2.22495pt" version="1.1" viewbox="0 0 5.9875002 14.85" width="5.9875002" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.017,-0,0,-.017,.062,12.012)"><path d="M290 -163h-170v866h170v-28q-79 -7 -94 -19.5t-15 -72.5v-627q0 -59 14.5 -71.5t94.5 -19.5v-28z" id="x5B"></path></g>
</svg>Ce<svg height="5.4499998" id="M79" style="vertical-align:-0.0pt" version="1.1" viewbox="0 0 4 5.4499998" width="4" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.017,-0,0,-.017,.062,5.388)"><path d="M170 255q0 -25 -16 -41t-40 -16t-40 16t-16 41t16 41.5t40 16.5t40 -16.5t16 -41.5z" id="x22C5"></path></g>
</svg>Lanso<svg height="5.4499998" id="M80" style="vertical-align:-0.0pt" version="1.1" viewbox="0 0 4 5.4499998" width="4" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.017,-0,0,-.017,.062,5.388)"><path d="M170 255q0 -25 -16 -41t-40 -16t-40 16t-16 41t16 41.5t40 16.5t40 -16.5t16 -41.5z" id="x22C5"></path></g>
</svg>Cyto·4H<sub>2</sub>O]SO<sub>4</sub>·<i>x</i>H<sub>2</sub>O</td><td align="center">1 : 1 :1 : 4H<sub>2</sub>O</td><td align="center">706</td></tr><tr><td align="left"><svg height="14.85" id="M81" style="vertical-align:-2.22495pt" version="1.1" viewbox="0 0 5.9875002 14.85" width="5.9875002" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.017,-0,0,-.017,.062,12.012)"><path d="M290 -163h-170v866h170v-28q-79 -7 -94 -19.5t-15 -72.5v-627q0 -59 14.5 -71.5t94.5 -19.5v-28z" id="x5B"></path></g>
</svg>Gd·Lanso·Cyto·4H<sub>2</sub>O]NO<sub>3</sub>·<i>x</i>H<sub>2</sub>O</td><td align="center">1 : 1 : 1 : 4H<sub>2</sub>O</td><td align="center">703</td></tr><tr><td align="left"><svg height="14.85" id="M82" style="vertical-align:-2.22495pt" version="1.1" viewbox="0 0 5.9875002 14.85" width="5.9875002" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.017,-0,0,-.017,.062,12.012)"><path d="M290 -163h-170v866h170v-28q-79 -7 -94 -19.5t-15 -72.5v-627q0 -59 14.5 -71.5t94.5 -19.5v-28z" id="x5B"></path></g>
</svg>Nd·Lanso·Cyto·4H<sub>2</sub>O]NO<sub>3</sub>·<i>x</i>H<sub>2</sub>O</td><td align="center">1 : 1 : 1 : 4H<sub>2</sub>O</td><td align="center">701</td></tr><tr class="table-tr"><td colspan="3"><hr class="tbody-hr"/></td></tr></table></td></tr></table>

Mass spectra of mixed ligand complexes of Lanso and Cyto.

Journal of Chemistry

tab6

Table 6

Table 6: Synthesis, Characterization, and Physicochemical Studies of Mixed Ligand Complexes of Inner Transition Metals with Lansoprazole and Cytosine 

Table 6 | Synthesis, Characterization, and Physicochemical Studies of Mixed Ligand Complexes of Inner Transition Metals with Lansoprazole and Cytosine 