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Journal of Chemistry
Volume 2013, Article ID 367617, 4 pages
Research Article

A New Heteroleptic Biquinoline Ruthenium(II) Sensitizer for Near-IR Sensitization of Nanocrystalline TiO2

1Inorganic and Physical Chemistry Division, CSIR-Indian Institute of Chemical Technology, Uppal Road, Tarnaka, Hyderabad 500607, India
2Photovoltaic Materials Unit, National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047, Japan
3Center of Excellence for Research in Engineering Materials (CEREM), College of Engineering, King Saud University, Riyadh 11421, Saudi Arabia

Received 22 June 2012; Accepted 14 October 2012

Academic Editor: Ahmed El-Shafei

Copyright © 2013 Surya Prakash Singh et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


Ruthenium(II) complex containing cis-[Ru(H2dcbiq)(L)(NCS)2], where H2dcbiq = 4,4′-dicarboxy-2,2′-biquinoline and L = 4,4′-di-tert-butyl-2-2′-dipyridyl coded as SPS-02, was synthesized and fully characterized. This complex showed appreciably broad absorption range. The new complex was used as photosensitizer in nanocrystalline TiO2 dye-sensitized solar cell application. cis-[Ru(H2dcbiq)(L)(NCS)2] (SPS-02) achieved efficient sensitization of nanocrystalline TiO2 over the whole visible range, extending into the near-IR region (ca. 1000 nm) with superior short-circuit photocurrent density ( = 9.13 mA cm−2) and conversion efficiency (η = 2.09%) compared with complex cis-[Ru(H2dcbiq)2(NCS)2] (1) under an irradiation of full sunlight (100 mW cm−2).