Synthesis, Structural Characterization, and Electrochemical Studies of New Oxovanadium(V) Complexes Derived from 2-Furanoylhydrazon Derivatives

Table 2

Selected bond lengths (Å) and angles (°) for 1.

Bond lengths
V1–O2	1.8480 (18)
V1–O3	1.9430 (17)
V1–O5	1.585 (2)
V1–N7	2.078 (2)
V1–O8	2.569 (2)
V1–O9	1.7652 (18)
O3–C14(C–O)	1.307 (3)
O2–C21(C–O)	1.337 (3)
N6–C14(C=N)	1.305 (3)
N7–C12(C=N)	1.297 (3)
N6–N7	1.396 (3)
O8–H81	0.837
Bond angles
O2–V1–O3	152.03 (8)
O2–V1–O5	99.87 (11)
O3–V1–O5	101.00 (10)
O2–V1–N7	84.07 (8)
O3–V1–N7	75.18 (7)
O5–V1–N7	96.74 (9)
O2–V1–O8	78.99 (8)
O3–V1–O8	77.77 (7)
O5–V1–O8	172.09 (9)
N7–V1–O8	75.37 (7)
O2–V1–O9	103.01 (8)
O3–V1–O9	89.51 (8)
O5–V1–O9	104.61 (11)
N7–V1–O9	155.81 (9)
O8–V1–O9	83.24 (8)
V1–O2–C21	133.69 (16)
V1–O3–C14	117.39 (15)
V1–N7–N6	116.56 (14)
V1–N7–C12	127.44 (17)