Kinetics and Mechanistic Studies on Oxidation of Levocarnitine by Bromamine-T in HCl Medium Catalyzed by Ru(III)

Table 1

Effect of varying concentrations of oxidant, substrate, acid and Ru(III) on the reaction rate at 303 K.

10^4[BAT] (mol dm^−3)	10^3[LC] (mol dm^−3)	10^3[HCl] (mol dm^−3)	10^6[RuCl3]; (mol dm^−3)	𝑘^′10^4 (s^−1)
5.0	10.0	10.0	6.0	3.02
10.0	10.0	10.0	6.0	3.00
20.0	10.0	10.0	6.0	3.10
10.0	1.0	10.0	6.0	1.60
10.0	5.0	10.0	6.0	2.47
10.0	10.0	10.0	6.0	3.00
10.0	20.0	10.0	6.0	3.63
10.0	30.0	10.0	6.0	4.26
10.0	10.0	1.0	6.0	0.70
10.0	10.0	5.0	6.0	2.01
10.0	10.0	10.0	6.0	3.02
10.0	10.0	20.0	6.0	4.80
10.0	10.0	10.0	0.0	0.65
10.0	10.0	10.0	2.0	1.49
10.0	10.0	10.0	4.0	2.25
10.0	10.0	10.0	6.0	3.00
10.0	10.0	10.0	8.0	3.72
10.0	10.0	10.0	10.0	4.50