Kinetics and Mechanistic Studies on Oxidation of Levocarnitine by Bromamine-T in HCl Medium Catalyzed by Ru(III)

Table 5

Effect of temperature on the reaction rate and activation parameters.

Temperature (K)	10^4𝑘^′ (s^−1)	10^4𝑘4 (s^−1)	Active parameters
			Parameter	Value
293	1.82	(2.63)	𝐸𝑎 (kJ mol^−1)	35.90 (41.10)
303	3.00	(4.30)	Δ𝐻 (kJ mol^−1)	33.38 (38.50)
313	4.62	(7.14)	Δ𝐺^# (kJ mol^−1)	94.82 (93.95)
323	7.30	(12.58)	Δ𝑆^# (J K^−1 mol^−1)	−202.79 (−182.74)

Values in parenthesis refer to the slow and rate limiting step.