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Journal of Chemistry
Volume 2013, Article ID 628253, 6 pages
http://dx.doi.org/10.1155/2013/628253
Research Article

A New Spectrophotometric Reagent for Fe(III): 2-(2,3-Dihydroxy-4-oxocyclobut-2-enylidene) Hydrozinecarbothiamide and Its Application in Real Samples

Department of Chemistry, Faculty of Science, Vali-e-Asr University of Rafsanjan, Rafsanjan, Iran

Received 19 February 2012; Revised 2 June 2012; Accepted 17 June 2012

Academic Editor: Dimosthenis L. Giokas

Copyright © 2013 Mahboubeh Saeidi et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

A new reagent 2-(2,3-dihydroxy-4-oxocyclobut-2-enylidene) hydrozinecarbothiamide has been synthesized and used for developing a simple spectrophotometric method for the determination of Fe(III) which is based on a 2 : 1 complex formation between Fe(III) and new reagent in aqueous solution. The method is optimized in terms of the pH value, amount of reagent required, ionic strength, and stability of the complex, sensitivity, linearity, and tolerance limits of various foreign ions. The complex is a red-brown chelate, with 𝜆 m a x = 4 6 5  nm at pH = 3 ( 𝜀 = 1 . 9 5 × 1 0 3 L mol−1 cm−1). The ionic strength was kept constant at 0.02 by adding appropriate amounts of NaCl solution. The calibration curve is linear in the concentration range from 0.27–33.50 μg mL−1. The effects of foreign ions on the determination of Fe(III) were investigated in order to assess the selectivity of the method. The method was applied in determination of Fe(III) in tap water, cow milk, and human serum.