Research Article
Synthesis, Structure, and Characterization of Keggin-Type Germanate
Table 2
Atomic coordinates (
) and equivalent isotropic displacement parameters (Ć
2) for I.
| | Atom | | | | Ueq |
| | Ge(1) | 2343(1) | 1584(1) | 920(1) | 67(1) | | Ge(2) | 1635(1) | 0 | 1913(1) | 64(1) | | Ge(3) | 1618(1) | 1618(1) | 0 | 64(1) | | Ge(4) | 1610(1) | 816(1) | 2731(1) | 67(1) | | Ge(5) | 2354(1) | 814(1) | 1853(1) | 68(1) | | Ge(6) | 2841(1) | 0 | 2440(1) | 76(1) | | Ge(7) | 2137(1) | 0 | 3306(1) | 78(1) | | Ge(8) | 2845(1) | 2110(1) | 0 | 81(1) | | F(1) | 1177(4) | 0 | 1416(4) | 71(3) | | F(2) | 1178(3) | 1178(3) | 0 | 72(5) | | F(3) | 3461(4) | 0 | 2555(6) | 97(4) | | F(4) | 3474(5) | 2196(5) | 0 | 115(5) | | F(5) | 2232(6) | 0 | 3995(6) | 125(5) | | O(1) | 1302(3) | 470(3) | 2294(4) | 71(3) | | O(2) | 2593(3) | 1242(3) | 1431(4) | 77(3) | | O(3) | 1251(4) | 1251(4) | 2997(5) | 73(4) | | O(4) | 1812(4) | 536(3) | 3311(4) | 81(3) | | O(5) | 2080(3) | 1091(3) | 2396(4) | 74(3) | | O(6) | 1945(3) | 1275(3) | 530(4) | 70(3) | | O(7) | 2850(3) | 1769(3) | 592(4) | 72(3) | | O(8) | 2065(3) | 2065(3) | 1236(5) | 71(4) | | O(9) | 2093(4) | 2093(4) | 0 | 64(5) | | O(10) | 1955(3) | 465(3) | 1512(4) | 67(3) | | O(11) | 2121(5) | 0 | 2435(5) | 66(4) | | O(12) | 2712(5) | 2712(5) | 0 | 88(7) | | O(13) | 2867(3) | 535(3) | 2061(4) | 72(3) | | O(14) | 2749(5) | 0 | 3154(6) | 84(4) | | O(1W) | 0 | 0 | 0 | 58(10) | | O(2W) | 0 | 5000 | 0 | 160(19) | | O(3W) | 1542(6) | 5000 | 0 | 78(7) | | N(1) | 474(4) | 474(4) | 554(6) | 60(4) | | N(2) | 1024(4) | 1024(4) | 1206(7) | 77(5) | | N(3) | 2517(5) | ā359(3) | 4395(4) | 69(4) | | N(4) | 1567(9) | 0 | 315(12) | 63(9) |
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Ueq is defined as one third of the trace of the orthogonalized Uij tensor.
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