Research Article

2-Hydroxy-1-naphthaldehyde-P-hydroxybenzoichydrazone: A New Chromogenic Reagent for the Determination of Thorium(IV) and Uranium(VI)

Table 1

Tolerance limits of foreign ions. Amount of Th(IV) taken = 0.928 μg mL−1 pH = 6.0.

Foreign ionTolerance limit
(μg mL−1)
Foreign ionTolerance limit
(μg mL−1)
Foreign ionTolerance limit
(μg mL−1)

Iodide 1904Ba(II)1650Hg(II)20
EDTA1861Na(I)1500Ru(III)20
Thiosulphate1680K(I)1400Mn(II)11
Sulphate1440Ca(II)1140Zr(IV)10
Bromide1215Mg(II)1000Sn(II)10
Citrate945W(VI)55Sr(II)9
Nitrate930Hf(IV)54Cr(VI)6
Tartrate 740Pb(II)42Cu(II)5
Thiocyanate870Ti(IV)40Ni(II)<1, 55a
Carbonate600Au(III)40Co(II)<1, 100a
Chloride533Te(IV)40Zn(II)<1, 60a
Phosphate475Cd(II)34Bi(III)<1, 150a
Thiourea380Se(IV)31Fe(II)<1, 60a
Oxalate280Mo(VI)29Al(III)<1, 120b
Fluoride95La(III)28U(VI)<1, 70b
Pd(II)22In(III)<1, 50b
Ag(I)22Ga(III)<1, 60b

Masking agents, ain the presence of 800 ppm of EDTA; b500 ppm of tartrate.