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Journal of Chemistry
Volume 2013, Article ID 703271, 10 pages
Research Article

Polyethylene Glycol Mediated Kinetic Study of Nitro Decarboxylation of α,β-Unsaturated Acids by Blau’s Fe(III) Phen Complex

1Department of Chemistry, CBIT, Gandipet, Hyderabad 500 075, India
2Department of Chemistry, Osmania University, Hyderabad 500 007, India

Received 17 May 2013; Accepted 11 August 2013

Academic Editor: Charles A. Mebi

Copyright © 2013 K. Ramesh et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Supplementary Material

Supplementary material given in Tables S.1 through S.20 shows “Effect of variation of [Phen] on First Order rate constant (k’) of various α, β-Unsaturated Acids in different PEG- 200 media at various temperatures”. From the slopes and intercepts of reciprocal plots 1/k’ Vs 1/[Phen] plots, formation constants(K1) and rate constant(k) were calculated. Data given in tables S.21 through S.25 show results of Eyring’s plots and in tables S.26 through S.30 show thermodynamic properties of complexation.

  1. Supplementary Tables