Table of Contents Author Guidelines Submit a Manuscript
Journal of Chemistry
Volume 2013 (2013), Article ID 717618, 10 pages
http://dx.doi.org/10.1155/2013/717618
Research Article

Hydrazine Complexes of Lanthanides with 3-Acetoxy- and 4-Acetoxybenzoic Acids: Spectroscopic, Thermal, and XRD Studies

1Department of Chemistry, Park College of Engineering and Technology, Kaniyur, Coimbatore 641659, India
2Department of Chemistry, Government College of Technology, Coimbatore 641013, India

Received 29 January 2012; Revised 20 May 2012; Accepted 29 May 2012

Academic Editor: Satoru Tsushima

Copyright © 2012 E. Helen Pricilla Bai and S. Vairam. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. J. R. J. Sorenson, “Copper chelates as possible active forms of the antiarthritic agents,” Journal of Medicinal Chemistry, vol. 19, no. 1, pp. 135–148, 1976. View at Google Scholar · View at Scopus
  2. D. A. Williams, D. T. Walz, and W. O. Foye, “Synthesis and biological evaluation of tetrakis(acetylsalicylato) μ dicopper(II),” Journal of Pharmaceutical Sciences, vol. 65, no. 1, pp. 126–129, 1976. View at Google Scholar · View at Scopus
  3. K. D. Rainsford and M. W. Whitehouse, “Concerning the merits of copper aspirin as a potential anti inflammaotry drug,” Journal of Pharmacy and Pharmacology, vol. 28, no. 1, pp. 83–86, 1976. View at Google Scholar · View at Scopus
  4. G. Smith, D. P. Arnold, C. H. L. Kennard, and T. C. W. Mak, “Tin(IV) porphyrin complexes-IV. Crystal structures of meso-tetraphenylporphyrinatotin(IV) complexes with hydroxide, water, benzoate, salicylate and acetylsalicylate as axial ligands,” Polyhedron, vol. 10, no. 4-5, pp. 509–516, 1991. View at Google Scholar · View at Scopus
  5. N. Arunadevi and S. Vairam, “3-hydroxy-2-naphthoate complexes of transition metals with hydrazine-preparation, spectroscopic and thermal studies,” E-Journal of Chemistry, vol. 6, supplement 1, pp. S413–S421, 2009. View at Google Scholar · View at Scopus
  6. S. Vairam, T. Premkumar, and S. Govindarajan, “Trimellitate complexes of divalent transition metals with hydrazinium cation thermal and spectroscopic studies,” Journal of Thermal Analysis and Calorimetry, vol. 100, no. 3, pp. 955–960, 2010. View at Publisher · View at Google Scholar · View at Scopus
  7. S. Vairam, T. Premkumar, and S. Govindarajan, “Preparation and thermal behaviour of divalent transition metal complexes of pyromellitic acid with hydrazine,” Journal of Thermal Analysis and Calorimetry, vol. 101, no. 3, pp. 979–985, 2010. View at Publisher · View at Google Scholar · View at Scopus
  8. B. N. Sivasankar and S. Govindarajan, “Acetate and malonate complexes of cobalt(II), nickel(II) and zinc(II) with hydrazinium cation: preparation, spectral and thermal studies,” Journal of Thermal Analysis, vol. 48, no. 6, pp. 1401–1413, 1997. View at Google Scholar · View at Scopus
  9. S. Yasodhai and S. Govindarajan, “Coordination compounds of some divalent metals with hydrazine and dicarboxylate bridges,” Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, vol. 30, no. 4, pp. 745–760, 2000. View at Google Scholar · View at Scopus
  10. K. Kuppusamy and S. Govindarajan, “Benzoate complexes of dipositive first row transition metal ions with hydrazine,” Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, vol. 26, no. 2, pp. 225–243, 1996. View at Google Scholar · View at Scopus
  11. K. Kuppusamy and S. Govindarajan, “Hydrazinium cation as a ligand preparation and spectral, thermal and XRD studies on hydrazinium metal phthalates,” Europe Journal of Solid State and Inorganic Chemistry, vol. 32, pp. 997–1012, 1995. View at Google Scholar
  12. I. A. Vogel, A Text Book of Quantitative Inorganic Analysis, Longmans, London, UK, 1975.
  13. W. T. Carnall, P. R. Fields, and K. Rajnak, “Spectral intensities of the trivalent lanthanides and actinides in solution. II. Pm3+, Sm3+, Eu3+, Gd3+, Tb3+, Dy3+, and Ho3+,” The Journal of Chemical Physics, vol. 49, no. 10, pp. 4400–4403, 1968. View at Google Scholar · View at Scopus
  14. S. P. Tanton and P. C. Mehta, “Study of some Nd3+ complexes : interelectronic repulsion, spin orbit interaction, bonding, and electronic energy levels,” Journal Chemical Physics, vol. 52, pp. 4896–4902, 1968. View at Google Scholar
  15. J. E. Huheey, E. A. Keiter, R. L. Keiter, O. K. Medhi et al., Inorganic Chemistry-Principles of Structure and Reactivity, vol. 488, Dorling Kindersley, New Delhi, India, 2007.
  16. J. L. Meier, C. E. Coughenour, J. A. Carlisle, and G. O. Carlisle, “The magnetic properties of a series of copper(II) aspirinates,” Inorganica Chimica Acta, vol. 106, no. 3, pp. 159–163, 1985. View at Google Scholar · View at Scopus
  17. A. L. Abuhijleh, C. Woods, E. Bogas, and G. Le Guenniou, “Synthesis, characterization and catecholase-mimetic activity of mononuclear copper(II) aspirinate complexes,” Inorganica Chimica Acta, vol. 195, no. 1, pp. 67–71, 1992. View at Google Scholar · View at Scopus
  18. S. H. Tarulli, O. V. Quinzani, J. Dristas, and E. J. Baran, “Thermal behaviour of copper(II) complexes of haloaspirinates,” Journal of Thermal Analysis and Calorimetry, vol. 60, no. 2, pp. 505–515, 2000. View at Publisher · View at Google Scholar · View at Scopus
  19. B. Raju and B. N. Sivasankar, “Spectral, thermal and X-ray studies on some new Bis-hydrazine lanthanide(III) glyoxylates,” Journal of Thermal Analysis and Calorimetry, vol. 94, no. 1, pp. 289–296, 2008. View at Publisher · View at Google Scholar · View at Scopus
  20. A. Braibanti, F. Dallavalle, M. A. Pellinghelli, and E. Leporati, “The nitrogen-nitrogen stretching band in hydrazine derivatives and complexes,” Inorganic Chemistry, vol. 7, no. 7, pp. 1430–1433, 1968. View at Google Scholar · View at Scopus
  21. K. C. Patil, G. V. Chandrashekhar, and C. N. R. Rao, “Infrared spectra and thermal decompositions of metal acetates and dicarboxylates,” Canadian Journal Chemistry, vol. 46, pp. 257–265, 1968. View at Google Scholar