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Journal of Chemistry
Volume 2013 (2013), Article ID 724163, 12 pages
http://dx.doi.org/10.1155/2013/724163
Research Article

Synthesis, Spectroscopic Characterization, and Biological Activities of Metal Complexes of 4-((4-Chlorophenyl)diazenyl)-2-((p-tolylimino)methyl)phenol

1Department of Chemistry, Fatima Michael College of Engineering & Technology, Madurai 625 020, India
2Department of Chemistry, The American College, Tamilnadu, Madurai 625 002, India
3Department of Chemistry, Thiagarajar College, Tamilnadu, Madurai 625 009, India

Received 10 June 2012; Accepted 20 August 2012

Academic Editor: Ai-Min Ren

Copyright © 2013 C. Anitha et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

Azo Schiff base complexes of VO(II), Mn(II), Co(II), Ni(II), Cu(II), and Zn(II) have been synthesized from 4-((4-chlorophenyl)diazenyl)-2-((p-tolylimino)methyl)phenol (CDTMP). The nature of bonding and the structural features of the complexes have been deduced from elemental analysis, molar conductance, magnetic susceptibility measurements, IR, UV-Vis, 1H-NMR, EPR, mass, SEM, and fluorescence spectral studies. Spectroscopic and other analytical studies reveal square-planar geometry for copper, square-pyramidal geometry for oxovanadium, and octahedral geometry for other complexes. The EPR spectra of copper(II) complex in DMSO at 300 K and 77 K were recorded, and its salient features are reported. Antimicrobial studies against several microorganisms indicate that the complexes are more potent bactericides and fungicides than the ligand. The electrochemical behavior of the copper(II) complex was studied by cyclic voltammetry. All the synthesized compounds can serve as potential photoactive materials as indicated from their characteristic fluorescence properties. The second harmonic conversion efficiency of the synthesized azo Schiff base was found to be higher than that of urea and KDP (potassium dihydrogen phosphate). SEM image of copper(II) complex implies the crystalline state and surface morphology of the complex.