Synthesis, Spectroscopic Characterization, and Biological Activities of Metal Complexes of 4-((4-Chlorophenyl)diazenyl)-2-((<i>p-</i>tolylimino)methyl)phenol

<table class="table-group" id="tab5"><tr><td><table class="table"><tr><td class="thead-hr" colspan="6"><hr/></td></tr><tr class="thead"><td align="left">Compound</td><td align="center"><i>υ </i><sub>
										2</sub>/<i>υ </i><sub>1</sub></td><td align="center"><i>B</i> (cm<sup>−1</sup>)</td><td align="center"><i>β</i></td><td align="center"><i>β</i>
                  °
                </td><td align="center">10Dq (cm<sup>−1</sup>)</td></tr><tr><td class="thead-hr" colspan="6"><hr/></td></tr><tr><td align="left"><svg height="14.85" id="M90" style="vertical-align:-2.22495pt" version="1.1" viewbox="0 0 5.9875002 14.85" width="5.9875002" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.017,-0,0,-.017,.062,12.012)"><path d="M290 -163h-170v866h170v-28q-79 -7 -94 -19.5t-15 -72.5v-627q0 -59 14.5 -71.5t94.5 -19.5v-28z" id="x5B"></path></g>
</svg>Co(CDTMP)<sub>2</sub>·2H<sub>2</sub>O] (<svg height="15.7" id="M91" style="vertical-align:-3.27605pt" version="1.1" viewbox="0 0 18.0375 15.7" width="18.0375" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.017,-0,0,-.017,.062,11.55)"><path d="M609 227h29l-42 -227h-577v25q56 8 70 20q16 13 16 53v478q0 42 -17.5 57t-68.5 18v25h348v-24q-64 -3 -83 -20q-17 -17 -17 -79v-464q0 -33 18.5 -45.5t66.5 -12.5q109 0 170 55q42 39 87 141z" id="x1D40B"></path></g>
<g transform="matrix(.012,-0,0,-.012,11.4,15.637)"><path d="M441 24v-24h-373v24q75 2 96 20q22 19 22 85v378q0 70 -36 70q-26 0 -65 -16l-20 -8v26l251 109h18v-570q0 -57 19 -75q19 -17 88 -19z" id="x1D7CF"></path></g>
</svg><b> 3</b>)</td><td align="center">1.25</td><td align="center">717</td><td align="center">0.74</td><td align="center">26</td><td align="center">10335</td></tr><tr><td align="left"><svg height="14.85" id="M92" style="vertical-align:-2.22495pt" version="1.1" viewbox="0 0 5.9875002 14.85" width="5.9875002" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.017,-0,0,-.017,.062,12.012)"><path d="M290 -163h-170v866h170v-28q-79 -7 -94 -19.5t-15 -72.5v-627q0 -59 14.5 -71.5t94.5 -19.5v-28z" id="x5B"></path></g>
</svg>Ni(CDTMP)<sub>2</sub>·2H<sub>2</sub>O] (<svg height="15.7" id="M93" style="vertical-align:-3.27605pt" version="1.1" viewbox="0 0 18.0375 15.7" width="18.0375" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.017,-0,0,-.017,.062,11.55)"><path d="M609 227h29l-42 -227h-577v25q56 8 70 20q16 13 16 53v478q0 42 -17.5 57t-68.5 18v25h348v-24q-64 -3 -83 -20q-17 -17 -17 -79v-464q0 -33 18.5 -45.5t66.5 -12.5q109 0 170 55q42 39 87 141z" id="x1D40B"></path></g>
<g transform="matrix(.012,-0,0,-.012,11.4,15.637)"><path d="M441 24v-24h-373v24q75 2 96 20q22 19 22 85v378q0 70 -36 70q-26 0 -65 -16l-20 -8v26l251 109h18v-570q0 -57 19 -75q19 -17 88 -19z" id="x1D7CF"></path></g>
</svg><b> 4</b>)</td><td align="center">1.52</td><td align="center">567</td><td align="center">0.55</td><td align="center">45</td><td align="center">10384</td></tr><tr class="table-tr"><td colspan="6"><hr class="tbody-hr"/></td></tr></table></td></tr></table>

Electronic parameters of Ni(II) and Co(II) complexes.

Journal of Chemistry

tab5

Table 5

Table 5: Synthesis, Spectroscopic Characterization, and Biological Activities of Metal Complexes of 4-((4-Chlorophenyl)diazenyl)-2-((<i>p-</i>tolylimino)methyl)phenol 

Table 5 | Synthesis, Spectroscopic Characterization, and Biological Activities of Metal Complexes of 4-((4-Chlorophenyl)diazenyl)-2-((p-tolylimino)methyl)phenol 