Research Article
Influence of Intercalation-Exfoliation-Reduction Technique towards the Physico-Chemical of VPO Catalysts
Table 2
Total amount of oxygen removed from the doped and undoped IER-VPD catalysts by reduction in H2/Ar.
| Catalyst (Peak) | (K) | Oxygen atom removed (Γ10-3βmolβgβ1) | Oxygen atom removed (Γ1021ββatomsβgβ1) | Ratio for oxygen removal of V5+/V4+ |
| IERC(2Bu-Et) | | | | | β1 | 802 | 0.22 | 0.13 | | β2 | 984 | 1.06 | 0.64 | 0.08 | β3 | 1060 | 1.50 | 0.90 | | Total oxygen atoms removed | | 2.78 | 1.67 | | IERC(2Bu-Et)RBi1 | | | | | β1 | 829 | 0.21 | 0.13 | | β2 | 941 | 2.57 | 1.55 | 0.08 | Total oxygen atoms removed | | 2.78 | 1.68 | | IERC(isoBu-Et) | | | | | β1 | 895 | 0.24 | 0.14 | | β2 | 1030 | 1.99 | 1.20 | 0.17 | Total oxygen atoms removed | | 2.23 | 1.34 | | IERC(isoBu) | | | | | β1 | 890 | 0.28 | 0.17 | | β2 | 1059 | 2.42 | 1.46 | 0.12 | Total oxygen atoms removed | | 2.70 | 1.63 | |
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