Research Article

Influence of Intercalation-Exfoliation-Reduction Technique towards the Physico-Chemical of VPO Catalysts

Table 2

Total amount of oxygen removed from the doped and undoped IER-VPD catalysts by reduction in H2/Ar.

Catalyst (Peak) 𝑇 m a x (K)Oxygen atom removed (Γ—10-3 mol gβˆ’1)Oxygen atom removed (Γ—1021  atoms gβˆ’1)Ratio for oxygen removal of V5+/V4+

IERC(2Bu-Et)
 18020.220.13
 29841.060.640.08
 310601.500.90
Total oxygen atoms removed2.781.67
IERC(2Bu-Et)RBi1
 18290.210.13
 29412.571.550.08
Total oxygen atoms removed2.781.68
IERC(isoBu-Et)
 18950.240.14
 210301.991.200.17
Total oxygen atoms removed2.231.34
IERC(isoBu)
 18900.280.17
 210592.421.460.12
Total oxygen atoms removed2.701.63