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Journal of Chemistry
Volume 2013, Article ID 748106, 6 pages
http://dx.doi.org/10.1155/2013/748106
Research Article

Separation and Preconcentration of Trace Amounts of Manganese and Nickel from Natural Water Samples by a Diimine Derivative Schiff Base-Coated Silica-Gel Minicolumn

Department of Chemistry, Payame Noor University, Tehran 19395-3697, Iran

Received 4 July 2012; Accepted 14 August 2012

Academic Editor: Daryoush Afzali

Copyright © 2013 Reyhaneh Rahnama and Mohammad Reza Jamali. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

An efficient method for preconcentration of trace amounts of Mn (II) and Ni (II) ions by using a minicolumn (10 mm × 30 mm i.d.) filled with a diimine derivative Schiff base on silica-gel has been reported. The retained analytes on the column were recovered with 5 mL of mixture of nitric acid 5 mol L−1 and methanol (1 : 1) and were determined by a flame atomic absorption spectrometer. Different factors including pH of sample solution, sample volume, amount of sorbent, eluent volume, and interference of other ions have been studied and the optimized conditions developed were utilized for the trace determination of Mn (II) and Ni (II) in natural water samples. The recoveries for the analytes under the optimum working conditions were higher than 98%. The relative standard deviations of the determinations (10 replicate analyses) at 25 μg L−1 of Mn (II) and Ni (II) were 2.5% and 2.3%, respectively. The limit of the detection (3s, for analytes were found to be 0.20 μg L−1 for Mn (II) and 0.15 μg L−1 for Ni (II). The proposed method was applied to the analysis of natural water samples with satisfactory results.