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Journal of Chemistry
Volume 2014, Article ID 450413, 6 pages
Research Article

Grafting of Gold Nanoparticles on Glass Using Sputtered Gold Interlayers

1Department of Solid State Engineering, Institute of Chemical Technology, 166 28 Prague, Czech Republic
2Faculty of Science, J. E. Purkyně University, 400 96 Usti nad Labem, Czech Republic

Received 13 November 2013; Accepted 12 May 2014; Published 16 June 2014

Academic Editor: Concha Gimeno

Copyright © 2014 Ondřej Kvítek et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


Three-step preparation of nanostructured Au layer on glass substrate is described. The procedure starts with sputtered gold interlayer, followed by grafting with dithiols and final coverage with gold nanoparticles (AuNPs). Successful binding of dithiols on the sputtered Au film was confirmed by X-ray photoelectron spectroscopy measurement. AuNPs bound to the surface were observed using atomic force microscopy. Both single nanoparticles and their aggregates were observed. UV-Vis spectra show broadening of surface plasmon resonance peak after AuNPs binding caused by aggregation of AuNPs on the sample surface. Zeta potential measurements suggest that a large part of the dithiol molecules are preferentially bound to the gold interlayer via both –SH groups.