Journal of Chemistry / 2015 / Article / Tab 1 / Research Article
A New Equation Relating the Viscosity Arrhenius Temperature and the Activation Energy for Some Newtonian Classical Solvents Table 1 Arrhenius parameters of some pure liquids studied at previous works, Arrhenius activation energy
(kJ·mol
−1 ), the logarithm of the entropic factor of Arrhenius
/Pa·s), the Arrhenius temperature (
/K), Arrhenius activation temperature (
/K), the melting point (
/K), and the boiling point (
/K).
Number Pure component Reference /K /kJ·mol−1 /K /K /K1 Acetone [11 ] 894.9 −11.097 7.4406 80.643 329.20 178.45 2 Acetic acid [11 ] 1348.6 −11.308 11.213 119.26 391.15 289.75 3 Aniline [11 ] 2405.1 −13.564 19.997 177.32 457.28 266.85 4 Butyl alcohol [11 ] 2298.9 −13.689 19.114 167.94 390.85 183.35 5 Carbone tetrachloride [11 ] 1242.3 −11.152 10.329 111.39 349.87 250.23 6 Ethyl acetate [11 ] 1192.9 −11.728 9.9183 101.72 350.15 189.55 7 Diethyl ether [11 ] 904.48 −11.446 7.5203 79.021 307.75 156.85 8 n-Heptane [11 ] 1036.7 −11.302 8.6196 91.723 371.15 182.55 9 n-Pentane [11 ] 733.64 −10.886 6.0998 67.393 309.25 143.45 10 Toluene [11 ] 1085.2 −11.135 9.0229 97.461 383.75 180.15 11 m -Xylene[11 ] 1052.2 −10.975 8.7485 95.872 412.25 225.35 12 n-Octanol [45 ] 3001.4 −14.945 24.955 200.83 468.15 257.15 13 Propylene glycol [46 ] 5744.8 −22.128 47.765 259.62 461.35 214.15 14 Butane-1,2-diol [47 ] 5281.1 −20.681 43.910 255.36 465.15 159.15 15 Butane-1,4-diol [47 ] 4012.2 −16.210 33.359 247.51 503.15 293.15 16 Propylene glycol [48 ] 4516.3 −18.266 37.551 247.25 461.35 214.15 17 1,2-Butanediol [48 ] 5624.3 −21.857 46.763 257.32 465.15 159.15 18 1,2-Butanediol [48 ] 5524.5 −21.510 45.933 256.84 465.15 159.15 19 1,4-Butanediol [48 ] 4093.3 −16.485 34.033 248.31 503.15 293.15 20 1,4-Butanediol [48 ] 4077.7 −16.438 33.904 248.07 503.15 293.15 21 Benzene [11 ] 1315.8 −11.812 10.940 111.39 353.15 278.65 22 Chlorobenzene [11 ] 1047.5 −10.695 8.7094 97.939 405.15 228.15 23 Ethylbenzene [11 ] 1095.8 −11.027 9.1110 99.375 409.15 178.15 24 o -Xylene[11 ] 1183.0 −11.145 9.8360 106.14 417.15 248.65 25 N,N-Dimethylacetamide [49 ] 1173.7 −10.914 9.7590 107.54 438.55 253.15 26 Formamide [49 ] 1973.7 −12.442 16.410 158.63 483.15 275.65 27 N,N-Dimethylformamide [49 ] 1088.8 −10.780 9.0530 101.00 425.00 212.15 28 N,N-Dimethylacetamide [50 ] 1133.7 −10.896 9.4260 104.05 438.55 253.15 29 Water [50 ] 1865.4 −13.284 15.510 140.42 373.15 273.15 30 2-Methoxyethanol [50 ] 1826.3 −12.602 15.185 144.93 397.65 188.15 31 N,N-Dimethylacetamide [51 ] 1178.3 −10.934 9.7973 107.77 438.55 253.15 32 2-Ethoxyethanol [51 ] 1900.7 −12.682 15.803 149.87 408.15 183.15 33 Water [52 ] 1914.7 −13.443 15.920 142.43 373.15 273.15 34 1,4-Dioxane [52 ] 1522.6 −11.853 12.660 128.47 374.15 284.15 35 Water [53 ] 1894.2 −13.383 15.749 141.54 373.15 273.15 36 Isobutyric acid [53 ] 1338.1 −11.200 11.126 119.48 426.65 226.15 37 Water [54 ] 1856.2 −13.232 15.433 140.28 373.15 273.15 38 Ethanol [54 ] 1588.1 −12.166 13.204 130.50 351.15 159.15 39 Water [55 ] 1881.1 −13.334 15.640 141.07 373.15 273.15 40 Methanol [55 ] 1194.8 −11.528 9.9340 103.64 337.75 175.55 41 Dimethylsulfoxide [56 ] 1690.8 −11.872 14.058 142.42 462.15 290.65 42 p -Xylene[56 ] 1009.3 −10.761 8.3920 93.800 411.15 285.65 43 Dimethylsulfoxide [57 ] 1723.9 −12.002 14.333 143.63 462.15 290.65 44 o -Xylene[57 ] 1151.4 −11.044 9.5730 104.26 417.15 248.65 45 Water [58 ] 2006.6 −13.742 16.684 146.02 373.15 273.15 46 1,4-Dioxane [58 ] 1403.5 −11.430 11.669 122.78 374.15 284.15 47 Ethylene glycol [58 ] 3601.1 −16.146 29.941 223.03 470.15 260.15 48 Triethyl amine [59 ] 987.68 −11.248 8.2120 87.810 361.95 158.15 49 Water [60 ] 1898.6 −13.389 15.786 141.80 373.15 273.15 50 Glycerol [61 ] 7169.2 −24.143 59.608 296.95 455.15 293.15 51 TEGMME [62 ] 2555.2 −13.638 21.245 187.36 395.15 229.15 52 n-Heptane [63 ] 1725.2 −12.613 14.344 136.78 371.15 182.15 53 1-Propanol [64 ] 2139.9 −13.415 17.792 159.51 370.15 149.15 54 2-Propanol [64 ] 2640.0 −15.032 21.950 175.63 355.15 183.65 55 t-Butanol [64 ] 3852.2 −18.476 32.029 208.50 355.55 298.84 56 Allyl alcohol [64 ] 1840.8 −12.866 15.305 143.07 370.15 144.15 57 Propargyl alcohol [64 ] 1816.7 −12.607 15.105 144.10 387.65 220.15 58 Dimethylsulfoxide [65 ] 1409.7 −10.975 11.721 128.44 462.15 290.65 59 Benzene [65 ] 1798.7 −13.254 14.955 135.71 353.15 278.65 60 Ethylbenzene [65 ] 1022.5 −10.807 8.5016 94.617 409.15 178.15 61 Chlorobenzene [65 ] 954.13 −10.406 7.9331 91.687 405.15 228.15 62 Bromobenzene [65 ] 2017.1 −13.450 16.771 149.98 429.15 242.15 63 1,4-Dioxane [66 ] 1452.2 −11.607 12.074 125.11 374.15 284.15 64 Ethanol [66 ] 1885.9 −12.997 15.680 145.10 351.15 159.15 65 2-Propanol [66 ] 3058.5 −16.403 25.430 186.46 355.15 183.65 66 Isoamyl alcohol [66 ] 2602.7 −14.322 21.640 181.72 403.15 156.15 67 3-Amino-1-propanol [66 ] 4336.9 −18.036 36.059 240.46 458.65 284.15 68 Water [67 ] 1872.4 −13.307 15.568 140.70 373.15 273.15 69 2-Methoxyethanol [67 ] 1744.4 −12.662 14.504 137.77 397.65 188.15 70 N-Methylacetamide [67 ] 2300.6 −13.155 19.128 174.88 478.15 300.15 71 Propylene carbonate [68 ] 1706.9 −11.729 14.192 145.53 513.15 218.15 72 1,2-Diethoxyethane [69 ] 910.34 −10.819 7.5690 84.142 394.15 199.15 73 Acetonitrile [70 ] 840.64 −10.793 6.9895 77.885 354.65 222.15 74 Methanol [71 ] 1226.5 −11.629 10.198 105.47 337.75 175.55 75 Tetrahydrofuran [71 ] 810.42 −10.393 6.7382 77.977 339.15 165.15
TEGMME is an abbreviation of triethylene glycol monomethyl ether.