Research Article

Novel Water Treatment Processes Based on Hybrid Membrane-Ozonation Systems: A Novel Ceramic Membrane Contactor for Bubbleless Ozonation of Emerging Micropollutants

Table 1

Oxidants, forms, and application methods [25].

OxidantFormsApplicationsApplication methodElectrical potential, V

FluorineNot usedNot used3.06
Hydroxyl radicalGenerated in specially designed reactors at the moment of use due to short lifeA, B, C, D2.80
OzoneOzone is a gas that is generated on-site by passing dry compressed air or pore oxygen across a high voltage electrodeB, C, DOzone is applied to water as a gas. Because mass transfer is an important issue, special attention is required for contractor design2.08
Peracetic acidStabilized liquid solutionA, DConcentrated solution mixed with water to be treated
Hydrogen peroxideLiquid solutionAConcentrated solution mixed with water to be treated1.78
PermanganateAvailable in bulk as granulesA, BAdded as a dry chemical using a feeder or as a concentrated solution (no more than five percent by weight due to its limited solubility)1.67
Chlorine, freeChlorine gas, NaOCl solutionA, DGas eductors and various diffuser designs1.49
Chlorine, combined (chloramines)Addition of ammonia: anhydrous ammonia gas, ammonium sulfate, and aqua ammonia (20 to 30 percent ammonia solution)A, DGas eductors, dry chemical feeders, and spray jets
Chlorine dioxideChlorine dioxide gas is produced on-site using a 25 percent sodium chlorite solution. The sodium chlorite solution reacts with the following constituents to form ClO2(g): (1) gaseous chlorine (Cl2), (2) aqueous chlorine (HOCl), or acid (usually hydrochloric acid, HCl)AGas eductors1.27
OxygenGas and liquidPure oxygen or the oxygen in air applied using diffusers or other devices1.23

A = oxidation of reduced inorganic species such as soluble metals, complexed metal species, and destruction of odor causing compounds.
B = oxidation of trace organic compounds, color and odor causing compounds, and NOM.
C = to improve coagulation.
D = used as a biocide to control algae in reservoirs and basins, for disinfection, and to control growth in distributions system.