Journal of Chemistry / 2015 / Article / Tab 2

Research Article

Synthesis and Crystal Structure of N-Dichloroacetyl-3,4-dihydro-3-methyl-6-chloro-2H-1,4-benzoxazine

Table 2

Selected bond lengths () and angles (°) for the title compound.

BondLength ()BondAngles (°)BondAngles (°)

Cl(1)-C(3)1.744(2)C(6)-O(1)-C(7)115.78(16)C(1)-C(6)-C(5)120.1(2)
Cl(2)-C(11)1.756(2)C(10)-N(1)-C(5)122.18(16)O(1)-C(7)-C(8)111.18(18)
Cl(3)-C(11)1.772(2)C(10)-N(1)-C(8)124.35(16)N(1)-C(8)-C(7)106.88(17)
O(1)-C(6)1.368(3)C(5)-N(1)-C(8)113.47(15)N(1)-C(8)-C(9)111.50(18)
O(1)-C(7)1.426(3)C(2)-C(1)-C(6)121.2(2)C(7)-C(8)-C(9)112.55(19)
O(2)-C(10)1.212(3)C(1)-C(2)-C(3)118.56(19)O(2)-C(10)-N(1)124.12(18)
N(1)-C(10)1.360(3)C(2)-C(3)-C(4)122.0(2)O(2)-C(10)-C(11)119.47(18)
N(1)-C(5)1.431(2)C(2)-C(3)-Cl(1)119.24(16)N(1)-C(10)-C(11)116.40(17)
N(1)-C(8)1.487(2)C(4)-C(3)-Cl(1)118.80(17)C(10)-C(11)-Cl(2)110.62(14)
C(1)-C(6)1.389(3)C(3)-C(4)-C(5)119.48(19)C(10)-C(11)-Cl(3)108.41(15)
C(1)-C(2)1.371(3)C(4)-C(5)-C(6)118.64(18)Cl(2)-C(11)-Cl(3)110.45(13)
C(5)-C(6)1.404(3)C(4)-C(5)-N(1)122.76(18)
C(7)-C(8)1.514(3)C(6)-C(5)-N(1)118.51(17)
C(8)-C(9)1.522(3)O(1)-C(6)-C(1)116.20(18)
C(10)-C(11)1.546(3)O(1)-C(6)-C(5)123.64(18)

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