Research Article

Sustainability Assessment of Chemical Processes: Evaluation of Three Synthesis Routes of DMC

Table 4

Process description for Route B.

Process unitTypeConditionsNotes

Reac 1Stoichiometric reactor = 100°C, = 140 barConversion of propylene oxide = 100%
Reac 2Stoichiometric reactor = 150°C, = 1 barConversion of methanol = 5.25%
Col 1 RadFrac column15 stages, distillate rate = 2, reflux ratio = 5Separation of propylene carbonate
Col 2RadFrac column15 stages, distillate rate = 1.895, reflux ratio = 5Separation of methanol
Col 3RadFrac column15 stages, distillate rate = 0.06, reflux ratio = 5Concentration of DMC after distillation = 85.9%
CondCooler = 20°C, = 1 barCooling of DMC