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Journal of Chemistry
Volume 2015, Article ID 561350, 7 pages
http://dx.doi.org/10.1155/2015/561350
Research Article

Ru-Sn-B/Al2O3 Catalysts for Selective Hydrogenation of Methyl Oleate: Influence of the Ru/Sn Ratio

Instituto de Investigaciones en Catálisis y Petroquímica (INCAPE) (FIQ-UNL, CONICET), Colectora Ruta Nacional, No. 168, Km. 0, Paraje El Pozo, 3000 Santa Fe, Argentina

Received 9 September 2015; Accepted 11 November 2015

Academic Editor: Antonio M. Romerosa-Nievas

Copyright © 2015 María A. Sánchez et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. I. V. Deliy, I. L. Simakova, N. Ravasio, and R. Psaro, “Catalytic behaviour of carbon supported platinum group metals in the hydrogenation and isomerization of methyl oleate,” Applied Catalysis A: General, vol. 357, no. 2, pp. 170–177, 2009. View at Publisher · View at Google Scholar · View at Scopus
  2. D. S. Brands, G. U-A-Sai, E. K. Poels, and A. Bliek, “Sulfur deactivation of fatty ester hydrogenolysis catalysts,” Journal of Catalysis, vol. 186, no. 1, pp. 169–180, 1999. View at Publisher · View at Google Scholar · View at Scopus
  3. L. Giraldo, G. Camargo, J. Tirano, and J. C. Moreno-Piraján, “Synthesis of fatty alcohols from oil palm using a catalyst of Ni-Cu supported onto Zeolite,” E-Journal of Chemistry, vol. 7, no. 4, pp. 1138–1147, 2010. View at Publisher · View at Google Scholar · View at Scopus
  4. D. A. Echeverri, J. M. Marín, G. M. Restrepo, and L. A. Rios, “Characterization and carbonylic hydrogenation of methyl oleate over Ru-Sn/Al2O3: effects of metal precursor and chlorine removal,” Applied Catalysis A: General, vol. 366, no. 2, pp. 342–347, 2009. View at Publisher · View at Google Scholar · View at Scopus
  5. T. Miyake, T. Makino, S.-I. Taniguchi et al., “Alcohol synthesis by hydrogenation of fatty acid methyl esters on supported Ru-Sn and Rh-Sn catalysts,” Applied Catalysis A: General, vol. 364, no. 1-2, pp. 108–112, 2009. View at Publisher · View at Google Scholar · View at Scopus
  6. M. J. Mendes, O. A. A. Santos, E. Jordão, and A. M. Silva, “Hydrogenation of oleic acid over ruthenium catalysts,” Applied Catalysis A: General, vol. 217, no. 1-2, pp. 253–262, 2001. View at Publisher · View at Google Scholar · View at Scopus
  7. K. De Oliveira, Y. Pouilloux, and J. Barrault, “Selective hydrogenation of methyl oleate into unsaturated alcohols in the presence of cobalt-tin supported over zinc oxide catalysts,” Journal of Catalysis, vol. 204, no. 1, pp. 230–237, 2001. View at Publisher · View at Google Scholar · View at Scopus
  8. K. D. O. Vigier, Y. Pouilloux, and J. Barrault, “High efficiency CoSn/ZnO catalysts for the hydrogenation of methyl oleate,” Catalysis Today, vol. 195, no. 1, pp. 71–75, 2012. View at Publisher · View at Google Scholar · View at Scopus
  9. Y. Pouilloux, F. Autin, A. Piccirilli, C. Guimon, and J. Barrault, “Preparation of oleyl alcohol from the hydrogenation of methyl oleate in the presence of cobalt–tin catalysts,” Applied Catalysis A: General, vol. 169, no. 1, pp. 65–75, 1998. View at Publisher · View at Google Scholar · View at Scopus
  10. K. Y. Cheah, T. S. Tang, F. Mizukami, S.-I. Niwa, M. Toba, and Y. M. Choo, “Selective hydrogenation of oleic acid to 9-octadecen-1-ol: catalyst preparation and optimum reaction conditions,” Journal of the American Oil Chemists' Society, vol. 69, no. 5, pp. 410–416, 1992. View at Publisher · View at Google Scholar · View at Scopus
  11. Y. Pouilloux, F. Autin, C. Guimon, and J. Barrault, “Hydrogenation of fatty esters over ruthenium-tin catalysts; characterization and identification of active centers,” Journal of Catalysis, vol. 176, no. 1, pp. 215–224, 1998. View at Publisher · View at Google Scholar · View at Scopus
  12. M. A. Sánchez, Y. Pouilloux, V. A. Mazzieri, and C. L. Pieck, “Influence of the operating conditions and kinetic analysis of the selective hydrogenation of oleic acid on Ru-Sn-B/Al2O3 catalysts,” Applied Catalysis A: General, vol. 467, no. 10, pp. 552–558, 2013. View at Publisher · View at Google Scholar · View at Scopus
  13. M. C. Schoenmaker-Stolk, J. W. Verwijs, and J. J. F. Scholten, “The catalytic hydrogenation of benzene over supported metal catalysts. III. Gas-phase hydrogenation of benzene over silica-supported Ru-Cu catalysts,” Applied Catalysis, vol. 30, no. 2, pp. 339–352, 1987. View at Publisher · View at Google Scholar · View at Scopus
  14. M. A. Sánchez, V. A. Mazzieri, M. Oportus, P. Reyes, and C. L. Pieck, “Influence of Ge content on the activity of Ru-Ge-B/Al2O3 catalysts for selective hydrogenation of methyl oleate to oleyl alcohol,” Catalysis Today, vol. 213, no. 9, pp. 81–86, 2013. View at Publisher · View at Google Scholar · View at Scopus
  15. S. A. D'Ippolito, C. R. Vera, F. Epron et al., “Catalytic properties of Pt-Re/Al2O3 naphtha-reforming catalysts modified by germanium introduced by redox reaction at different pH Values,” Industrial and Engineering Chemistry Research, vol. 48, no. 8, pp. 3771–3778, 2009. View at Publisher · View at Google Scholar · View at Scopus
  16. M. A. Sánchez, V. A. Mazzieri, M. A. Vicerich, C. R. Vera, and C. L. Pieck, “Influence of the support material on the activity and selectivity of Ru–Sn–B catalysts for the selective hydrogenation of methyl oleate,” Industrial & Engineering Chemistry Research, vol. 54, no. 27, pp. 6845–6854, 2015. View at Publisher · View at Google Scholar
  17. R. Burch, “Platinum-tin reforming catalysts: I. The oxidation state of tin and the interaction between platinum and tin,” Journal of Catalysis, vol. 71, no. 2, pp. 348–359, 1981. View at Publisher · View at Google Scholar · View at Scopus
  18. B. A. Sexton, A. E. Hughes, and K. Foger, “An X-ray photoelectron spectroscopy and reaction study of Pt-Sn catalysts,” Journal of Catalysis, vol. 88, no. 2, pp. 466–477, 1984. View at Publisher · View at Google Scholar · View at Scopus
  19. V. A. Mazzieri, F. Coloma-Pascual, A. Arcoya, P. C. L'Argentière, and N. S. Fígoli, “XPS, FTIR and TPR characterization of Ru/Al2O3 catalysts,” Applied Surface Science, vol. 210, no. 3-4, pp. 222–230, 2003. View at Publisher · View at Google Scholar · View at Scopus
  20. A. Bossi, F. Garbassi, A. Orlandi, G. Petrini, and L. Zanderighi, “Preparation aspects of Ru-supported catalysts and their influence on the final products,” Studies in Surface Science and Catalysis, vol. 3, pp. 405–416, 1979. View at Publisher · View at Google Scholar
  21. M. Boudart, “Catalysis by supported metals,” Advances in Catalysis, vol. 20, pp. 153–166, 1969. View at Publisher · View at Google Scholar · View at Scopus
  22. C. R. Lederhos, J. M. Badano, N. Carrara et al., “Metal and precursor effect during 1-heptyne selective hydrogenation using an activated carbon as support,” The Scientific World Journal, vol. 2013, Article ID 528453, 9 pages, 2013. View at Publisher · View at Google Scholar · View at Scopus
  23. L. S. Carvalho, C. L. Pieck, M. C. Rangel et al., “Trimetallic naphtha reforming catalysts. I. Properties of the metal function and influence of the order of addition of the metal precursors on Pt–Re–Sn/γ-Al2O3–Cl,” Applied Catalysis A: General, vol. 269, no. 1-2, pp. 91–103, 2004. View at Google Scholar
  24. J. L. Margitfalvi, I. Borbáth, M. Hegedüs, S. Göbölös, and F. Lónyi, “New approaches to prepare supported Sn−Pt bimetallic catalysts,” Reaction Kinetics and Catalysis Letters, vol. 68, no. 1, pp. 133–143, 1999. View at Publisher · View at Google Scholar · View at Scopus
  25. R. Gomez, V. Bertin, P. Bosch, T. Lopez, P. Del Angel, and I. Schifter, “Pt-Sn/Al2O3 sol-gel catalysts: metallic phase characterization,” Catalysis Letters, vol. 21, no. 3-4, pp. 309–320, 1993. View at Publisher · View at Google Scholar · View at Scopus
  26. H. Verbeek and W. M. H. Sachtler, “The study of the alloys of platinum and tin by chemisorption,” Journal of Catalysis, vol. 42, no. 2, pp. 257–267, 1976. View at Publisher · View at Google Scholar · View at Scopus
  27. T. Narita, H. Miura, K. Sugiyama, T. Matsuda, and R. D. Gonzalez, “The effect of reduction temperature on the chemisorptive properties of Ru SiO2: effect of chlorine,” Journal of Catalysis, vol. 103, no. 2, pp. 492–495, 1987. View at Publisher · View at Google Scholar · View at Scopus
  28. E. A. Seddon and K. R. Seddon, “The chemistry of ruthenium,” in Topics in Inorganic and General Chemistry, R. J. H. Clark, Ed., chapter 3, Elsevier Science Publisher BV, Amsterdam, The Netherlands, 1984. View at Google Scholar
  29. S. H. Xie, M. H. Qiao, H. X. Li, W. J. Wang, and J.-F. Deng, “A novel Ru-B/SiO2 amorphous catalyst used in benzene-selective hydrogenation,” Applied Catalysis A: General, vol. 176, no. 1, pp. 129–134, 1999. View at Publisher · View at Google Scholar · View at Scopus
  30. J. F. Moulder, W. F. Stickle, and P. E. Sobol, Handbook of X-ray Photoelectron Spectroscopy, Perkin-Elmer Corporation-Elmer, Waltham, Mass, USA, 1992.
  31. C. Elmasides, D. I. Kondarides, W. Grünert, and X. E. Verykios, “XPS and FTIR study of Ru/Al2O3 and Ru/TiO2 catalysts: reduction characteristics and interaction with a methane-oxygen mixture,” The Journal of Physical Chemistry B, vol. 103, no. 25, pp. 5227–5239, 1999. View at Google Scholar · View at Scopus
  32. Y. Okamoto, Y. Nitta, T. Imanaka, and S. Teranishi, “Surface characterisation of nickel boride and nickel phosphide catalysts by X-ray photoelectron spectroscopy,” Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, vol. 75, pp. 2027–2039, 1979. View at Publisher · View at Google Scholar · View at Scopus
  33. S. R. Adkins and B. H. Davis, “The chemical state of tin in platinum-tin-alumina catalysts,” Journal of Catalysis, vol. 89, no. 2, pp. 371–379, 1984. View at Publisher · View at Google Scholar · View at Scopus
  34. V. M. Deshpande, K. Ramnarayan, and C. S. Narasimhan, “Studies on ruthenium-tin boride catalysts II. Hydrogenation of fatty acid esters to fatty alcohols,” Journal of Catalysis, vol. 121, no. 1, pp. 174–182, 1990. View at Publisher · View at Google Scholar · View at Scopus