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Journal of Chemistry
Volume 2015, Article ID 946462, 9 pages
Research Article

Filter Cake Oil-Wax as Raw Material for the Production of Biodiesel: Analysis of the Extraction Process and the Transesterification Reaction

1Department of Chemical Engineering and Food Technology, Faculty of Science, International Agrifood Campus of Excellence (ceiA3), University of Cadiz, Puerto Real, 11510 Cadiz, Spain
2Department of Chemistry, Faculty of Chemistry and Pharmacy, Central University of Las Villas, Santa Clara, 50100 Villa Clara, Cuba

Received 11 December 2014; Accepted 23 February 2015

Academic Editor: Veera Gnaneswar Gude

Copyright © 2015 L. Casas et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


The viability of using the waste obtained in the manufacture of sugar from sugarcane for the production of biodiesel has been analyzed. Two fundamental stages are necessary to obtain biodiesel; the first stage is the extraction process from the waste oil materials and the second is the transesterification reaction. Four techniques, Soxhlet, orbital shaker extraction, ultrasonic-assisted extraction, and supercritical fluid extraction, have been analyzed. For Soxhlet, orbital shaker extraction, and ultrasonic-assisted extraction, the organic solvent (hexane) was maintained for all experiment. In supercritical fluid extraction two solvents were evaluated: pure CO2 and mixtures of CO2 and 5% (v : v) methanol. The reaction kinetics of the transesterification reaction with an acidic catalyst and a basic catalyst were analysed. The results show that the supercritical extraction process produces a better product for the subsequent transesterification reaction. This finding is attributed to the high selectivity of carbon dioxide in the recovery of fatty acids and triglycerides in comparison with other solvents.