Exploring the Ruthenium-Ligands Bond and Their Relative Properties at Different Computational Methods

Table 1

The experimental bond distances for Ru-L which are found to be common in different ruthenium complexes.

Ru-C	Ru-N	Ru-O	Ru-P	Ru-S	Ru-Cl	Ru-H
1.827 [44]	1.940 to 2.137 [45]	2.00 to 2.01 [46]	2.2587 to 2.3141 [47]	2.246 to 2.266 [48]	2.2971 to 2.3680 [49]	1.494 [44]
1.845 to 2.220 [50]	2.00 to 2.053 [46]	2.0514 to 2.091 [47]	2.277 [50]	2.2777 to 2.3050 [51]	2.327 to 3.366 [51]	1.57 to 1.59 [52]
1.865 to 2.035 [53]	2.0190 to 2.0914 [49]	2.058 to 2.074 [54]	2.279 to 2.298 [54]	2.3436 to 2.3737 [55]	2.359 to 2.388 [45]
2.083 [1]	2.024 to 2.114 [51]	2.0656 [51]	2.2812 to 2.4188 [52]		2.3726 to 2.3885 [53]
2.109 to 2.287 [55]	2.025 to 2.047 [46]	2.066 to 2.092 [44]	2.31 to 2.389 [47]		2.407 to 2.418 [37]
2.116 to 2.1777 [43]	2.066 to 2.196 [56]	2.076 to 2.109 [49]	2.3165 to 2.3679 [57]		2.407 to 2.4511 [46]
2.199 to 2.281 [58]	2.0703 to 2.183 [53]	2.0783 to 2.118 [53]	2.336 [46]		2.411 to 2.434 [54]
	2.0792 [58]	2.18 to 2.23 [59]	2.363 to 2.378 [44]		2.431 to 2.4823 [47]
	2.107 to 2.122 [60]		2.412 [56]		2.434 to 2.4567 [51]
	2.141 to 2.196 [44]				2.4357 [1]