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Journal of Chemistry
Volume 2016 (2016), Article ID 5620316, 6 pages
http://dx.doi.org/10.1155/2016/5620316
Research Article

Study on Low-Temperature Catalytic Dehydrogenation Reaction of Tail Chlorine by Pd/Al2O3

College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, China

Received 1 June 2016; Revised 26 September 2016; Accepted 18 October 2016

Academic Editor: Hossein Kazemian

Copyright © 2016 Hanhan Wang et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

The catalytic dehydrogenation reaction of tail chlorine by Pd was studied using a fixed-bed reactor at low temperature from 30 to 100°C. Different catalyst supports such as SiO2 and Al2O3 were applied to prepare Pd catalysts by the incipient-wetness impregnation method. And the catalysts were characterized by XRD, FTIR, XPS, SEM, and N2 adsorption-desorption. The catalyst Pd loading on both SiO2 and Al2O3 had a catalytic effect on the dehydrogenation reaction, but the carrier Al2O3 was more superior. The hydrogen conversion and selectivity of hydrogen-oxygen reaction increased first and then decreased with Pd loading amount and temperature by using Pd/Al2O3 as catalysts, but the influence of temperature was limited when it was higher than 60°C. The hydrogen conversion was 97.38% and selectivity of hydrogen-oxygen reaction was 79% when the reaction temperature was at 60°C with 1 wt.% Pd/Al2O3.