Research Article

Protonation and Solvation Thermodynamics of Some Naphthol Derivatives in KCl Aqueous Solution of Different Ionic Strengths

Table 4

The protonation constants at infinite dilution () and parameters ( and ) for the dependence of the protonation constants on ionic strength for L1, L2, and L3 at different temperatures.

Ligand293.15 K298.15 K303.15 K308.15 K313.15 K

L19.469.459.449.429.40
0.270.260.280.260.27
0.020.020.030.020.03

L210.1910.1710.1610.1410.13
0.380.360.370.360.37
0.950.930.930.950.94
8.898.868.858.848.82
0.250.230.240.230.24
0.210.260.230.250.21

L310.3710.3510.3310.3210.30
0.770.750.730.720.77
0.090.080.070.080.09
8.468.448.428.438.40
0.460.480.490.490.50
0.030.020.030.020.01
1.311.291.271.261.24
0.480.450.430.460.46
0.020.020.030.020.03