Research Article

Protonation and Solvation Thermodynamics of Some Naphthol Derivatives in KCl Aqueous Solution of Different Ionic Strengths

Table 9

The standard thermodynamic parameters of protonation process ((  kJ mol−1), (  kJ mol−1), and (  kJ mol−1⋅K−1)) of L1, L2, and L3 at different temperatures (/K).

Ligand293.15298.15303.15308.15313.15

L1−53.018−53.866−54.712−55.497−56.278−3.7210.169

L2−57.110−57.970−58.888−59.739−60.649−5.2580.177
−49.824−50.503−51.293−52.080−52.806−7.4740.144

L3−58.118−58.996−59.870−60.799−61.667−5.9620.178
−47.414−48.109−48.800−49.665−50.291−4.5570.146
−7.342−7.353−7.361−7.423−7.424−5.9630.005