Table of Contents Author Guidelines Submit a Manuscript
Journal of Chemistry
Volume 2016, Article ID 7604748, 9 pages
http://dx.doi.org/10.1155/2016/7604748
Research Article

Preparation of Magnetic Nanoparticles via a Chemically Induced Transition: Presence/Absence of Magnetic Transition on the Treatment Solution Used

School of Physical Science and Technology, Southwest University, Chongqing 400715, China

Received 26 November 2015; Accepted 13 December 2015

Academic Editor: José L. A. Mediano

Copyright © 2016 Yanshuang Chen et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

The dependence of magnetic transition on the treatment solution used in the preparation of magnetic nanoparticles was investigated using as-prepared products from paramagnetic FeOOH/Mg(OH)2 via a chemically induced transition. Treatment using FeCl3 and CuCl solutions led to a product that showed no magnetic transition, whereas the product after treatment with FeSO4 or FeCl2 solutions showed ferromagnetism. Experiments revealed that the magnetism was caused by the ferrimagnetic γ-Fe2O3 phase in the nanoparticles, which had a coating of ferric compound. This observation suggests that Fe2+ in the treatment solution underwent oxidation to Fe3+, thereby inducing the magnetic transition. The magnetic nanoparticles prepared via treatment with an FeSO4 solution contained a larger amount of the nonmagnetic phase. This resulted in weaker magnetization even though these nanoparticles were larger than those prepared by treatment with an FeCl2 solution. The magnetic transition of the precursor (FeOOH/Mg(OH)2) was dependent upon treatment solutions and was essentially induced by the oxidation of Fe2+ and simultaneous dehydration of FeOOH phase. The transition was independent of the acid radical ions in the treatment solution, but the coating on the magnetic crystallites varied with changes in the acid radical ion.