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Journal of Chemistry
Volume 2016, Article ID 8105128, 9 pages
http://dx.doi.org/10.1155/2016/8105128
Research Article

A Comparative Electrochemical-Ozone Treatment for Removal of Phenolphthalein

1Facultad de Química, Universidad Autónoma del Estado de México, Paseo Colón, Intersección Paseo Tollocan S/N, 50120 Toluca, MEX, Mexico
2Centro Conjunto de Investigación en Química Sustentable UAEM-UNAM, Carretera Toluca-Atlacomulco, Km 14.5, Campus San Cayetano, 50200 Toluca, MEX, Mexico
3Centro Interamericano de Recursos del Agua, Universidad Autónoma del Estado de México, C.P. 50091 Toluca, MEX, Mexico

Received 15 July 2016; Revised 15 September 2016; Accepted 21 September 2016

Academic Editor: Julie J. M. Mesa

Copyright © 2016 V. M. García-Orozco et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

The degradation of aqueous solutions containing phenolphthalein was carried out using ozone and electrochemical processes; the two different treatments were performed for 60 min at pH 3, pH 7, and pH 9. The electrochemical oxidation using boron-doped diamond electrodes processes was carried out using three current density values: 3.11 mA·cm−2, 6.22 mA·cm−2, and 9.33 mA·cm−2, whereas the ozone dose was constantly supplied at  mgL−1. An optimal degradation condition for the ozonation treatment is at alkaline pH, while the electrochemical treatment works better at acidic pH. The electrochemical process is twice better compared with ozonation.

1. Introduction

Water is one of the most valuable assets for a country; indeed, safe drinking water is a basic human right. Safe and reliable drinking water is vital to every community since human health has become expensive since inadequate water quality reduces work productivity [1, 2]. Water scarcity is an economic threat for developing countries in which a large amount is used in agricultural, industrial, and domestic purposes [3].

Wastewater treatment has become a priority since good quality treated wastewater can be reused in some activities. An effective approach for treating wastewater is to carry out treatments in well-located sources. In this sense, water and wastewater testing laboratories generate large amounts of residues. In particular, the analysis and test for alkalinity and acidity using phenolphthalein (PHPH) produce large amounts of wastewater containing PHPH. In industrial operations such as the flavour drinking water industry, the mixing reactors in which the water is prepared should be cleaned after the process; this is commonly done using an aqueous solution containing NaOH, and then rinsing water containing PHPH is used for checking that all NaOH has been eliminated.

PHPH was discovered by the German chemist Adolf von Baeyer in 1871. He prepared it by the fusion of phenol and phthalic anhydride in the presence of sulfuric acid or Zinc chloride [4, 5].

PHPH (1%) is used in alcoholic solutions in titration as a pH visual indicator to unveil information regarding other compounds that include some organic and mineral acids as well as most alkalis. When working as an indicator, it turns pink in basic solutions usually above pH 10 and colorless in acidic ones below pH 8 [6]. Furthermore, it is utilized to forecast depth of concrete carbonation. A different application for PHPH is in determination of diluted blood used for forensic evidences such as Kastle-Meyer test. Here, the color turns pink if the specimen analyzed contains haemoglobin. Likewise, PHPH is used as the staple ingredient to make disappearing dye in some toys [7]. PHPH can be traced in an assortment of ingested products and in some scientific applications too. Furthermore, it could be incorporated in tablets, powders, and liquids because of its odourless and tasteless features. Additionally, it is employed as a laxative, in the form of a gum laxative product or chocolate [8]. In 1999 [9], PHPH was removed from Over-the-Counter medication (OTC) laxatives by the Food and Drug Administration (FDA). Recently, PHPH test indicates that it could cause neoplasia and ovary cancer [1012].

The use of advanced oxidation processes (AOPs) allows producing hydroxyl radicals, which are strong oxidant agents, ready to react with organics [1316]. Unlike many other radicals, hydroxyl radicals are nonselective and thus readily attack a big group of organic chemicals to transform them into less complex and damaging intermediate products that can degrade in an indiscriminate way of micropollutants [17]; these ones possess reaction rate constants around 109 Lmol−1 s−1 [18].

Among others, electrooxidation and ozonation can produce hydroxyl radicals. Until now there are few studies in which both processes are used at the same time; indeed, PHPH degradation has not previously been reported.

2. Materials and Methods

2.1. Chemicals

Distilled water was used for the preparation of aqueous solutions, used as synthetic water prepared with PHPH (Técnical Química) at 5 mg/L. Na2SO4 (Fermont) at 0.05 M was selected as the support electrolyte in this work. The electrolytic medium was made basic, neutral, and acidic as required by the addition of aqueous B(OH)3 (J. T. Baker at 0,04 M), H3PO4 (Merck at 0,04), and H2SO4 (Fermont at 1 M), where B(OH)3 and H3PO4 (Merck) were used as buffer for maintaining the pH of 9 and 7 with the addition of NaOH (Merck at 5 M), respectively.

2.2. Electrooxidation Treatment

For this process a batch type reactor with cylindrical shape containing electrodes of boron-doped diamond (BDD) was used, where the electrodes were connected in parallel and each electrode is 20.6 cm large per 2.6 cm wide. Three electrodes were used as anodes and two as cathodes. The total anodic surface (Aa) was 321.36 cm2. While the capacity of the reactor was 1.2 L, 1.0 L was used at all experiments. 1–3 A (3.11, 6.22, and 9.33 mA·cm−2) were supplied during all the process. Three different pH values were studied 3, 7, and 9. Aliquots were taken at different elapsed times (Figure 1(a)).

Figure 1: Schematic diagram: (a) electrooxidation treatment; (b) ozonation treatment.
2.3. Ozonation Treatment

In this treatment ozone was supplied by a Pacific Ozone Technology generator number LAB212 with Serial Number 7646; ozone was produced using dry air. The reactor is 40 cm long and 8 cm in diameter, and one liter of contaminated solution was used for the test. The reactor was fed, with ozone, in the bottom part through a porous plate, with a constant concentration of  mgL−1. Ozonation experiments were carried out at the pH of 3, 7, and 9, and samples were taken at regular intervals to determine the chemical oxygen demand (COD).

Ozone not used in the reaction was collected in the upper part of the reactor and directed to a heated catalytic ozone destruct, PACIFIC OZONE, Model Number d42202, with Serial Number 1687 (Figure 1(b)).

2.4. Analytic Methods

The aliquots were characterized before and after the treatment. In this characterization, COD was measured in accordance with APHA/AWWA/WPCE.

The concentration of total organic carbon (TOC) of each sample was measured in a Shimadzu Total Organic Carbon Analyzer (model ) fitted with an autosampler [19].

The removal efficiency or percentage of COD removal (%RE) was then calculated as follows [20]:The instantaneous current efficiency (ICE) can be used to calculate the apparent Faradic efficiency of COD removal by using the following formula [21]:The energy consumption () per unit COD mass (KWh mg−1 COD) was calculated using [22] then and are the COD values (gO2·dm−3) at and +  (s), respectively, is the current intensity (A), is the Faraday constant (96487 Cmol−1), is the electrolyte solution volume (L), the constant 8 is the oxygen equivalent mass (g eq.−1), and is the average cell voltage (V).

Converting m3 to dm3 considering 1000 dm3 equals 1 m3 and taking into account that the cost of electricity in US is 0.15 (U.S. currency) per kWh, the monetary value required to demean a unit of volume effluent is given by the equation below [23]:

3. Results and Discussions

3.1. UV-Vis Characterization

Figure 2(a) shows the ultraviolet-visible spectroscopy (UV-Vis) absorption spectra, of a 5 mgL−1 PHPH solution at pH 3, 7, and 9. All spectra present two absorption bands. At pH 3 and 7, however, they have an absorbance maximum in the wavelength () of 229 nm, unlike at pH 9, where such a maximum is located in 234 nm. This is related to the protonated structure of the PHPH and agrees with the species distribution diagram found as described in Figure 2(b) (pka of PHPH is 9.7 [7, 24, 25]); the second of the three spectra is in 274 nm, which corresponds to the 100% of the acid specie at pH 3 and 7. At pH 9, a change in these bands is observed, because there are 84% of acidic species PHPH and 16% of basic species; additionally, an absorption band with an absorbance maximum of 554 nm is formed, which is associated with the pink color and is a consequence of the structure of the molecule formed in basic pH.

Figure 2: (a) UV-Vis PHPH peaks at different pH values: () 9, (—) 7, and (--) 3. (b) Chemical species distribution diagram, protonated and deprotonated: () C20H14O4 and () C20H12O4.
3.2. Effect of Current Density in Electrooxidation Treatment

The effect of current densities () (3.11 mA·cm−2, 6.22 mA·cm−2, and 9.33 mA·cm−2) was studied to find the current density optimum value.

Figure 3(a) shows the removal of the PHPH using the COD; the process was performed at 60 minutes; taking aliquots every 10 minutes, the initial concentration of the PHPH was 5 mgL−1, at pH 3. The current density that shows a greater removal of the COD is 9.33 mA·cm−2 obtaining a 71% COD decrease.

Figure 3: (a) Influence of the current density in the COD removal; (b) UV-Vis spectra: () PHPH solution in the electrooxidation treatment to pH () 3.11, (⧫) 6.22, and () 9.33 mA⋅cm−2.

In previous reports the treatment time is associated with pollutant and color removal [26].

Figure 3(b) depicts the absorption spectra acquired during the treatment at the three current densities previously mentioned. This technique confirms how the PHPH is eliminating. The pollutant removal occurs by the hydroxyl radical reactions formed in the electrooxidation treatment. Hydroxyl radical () formation occurs at the DDB surface [27]; its high oxidizing power oxidizes the organic material as shown in reaction (5) [2831] and generates oxygen evolution. In this process it is possible to reach complete mineralization, where CO2 and H2O are formed according to Equations (6) and (7), and then CO2 can be hydrolyzed to form carbonate ions [32, 33].Reactions (6) and (7) compete with the secondary reaction of hydroxyl radical transformation to O2 without any participation of the anode surface as indicated in the following equation [34]:The energy consumption is shown in Table 1.

Table 1: Energy consumption to amperages and different pH.

The optimal conditions for the electrooxidation treatment are presented in Figure 4(a); as shown, the acidic pH is more effective. The spectrum change after the treatment, as illustrated in Figure 4(b), which shows that the greater COD decreases is at pH 3. It can be concluded that the optimal conditions are a current density of 6.22 mA·cm−2 and using pH of 3.

Figure 4: (a) Influence of the COD removal; (b) UV-Vis spectra: () PHPH solution in the electrooxidation treatment to pH () 9, () 7, and (○) 3.

Figure 5 shows the efficiency of the instantaneous current during the treatment of 6.22 mA·cm−2, which also shows the lowest ICE (80%). This value indicates that almost all the energy is used in the degradation and there is little lost energy; this result agrees with previous works [35].

Figure 5: Instant Current Efficiency in the electrooxidation treatment to () using a current density of 6.22 mA⋅cm−2.

The better ICE percentage is found at the beginning stage of electrooxidation and it may be attributed to the presence of higher concentration of organics in the vicinity of the electrodes. This indicates that the electrooxidation is under current control regime at least in the middle stage of electrooxidation. It was observed that ICE decreased during the electrooxidation process. This may be explained due to the depletion of organics concentration in the vicinity of electrode surface [36].

3.3. Ozonation Treatment

The ozone was generated by an ozone generator (Equation (9)); the presence of ozone in the system generates the radicals (Equation (10)) that carry out the oxidation of the PHPH [37, 38]. Ozone has an oxidation potential of 2.07 v [39, 40]. Figure 6(a) shows a 26% COD removal at pH 9; in pH 7 only 11% is reached, but at pH 3 only 1% of the PHPH is removed after 60 minutes of treatment time. The main reactions (11)–(13) where hydroxyl radicals are formed are shown below: [4144].The general stoichiometry occurs by the following equations, depending on whether the initiation is hydroxyl ions [41].The hastened ozone decomposition resulted in the rapid production of , leading to the higher removal of PHPH [43].We present reactions that occur during the ozonation process in Equations (9)–(13); this indicates that fragmentation of the molecule PHPH is taking place and not a degradation.

Figure 6: (a) Influence of the COD removal; (b) UV-Vis spectra: () PHPH solution in the ozonation treatment to pH () 3, () 7, and () 9.
3.4. TOC Removal Comparison between Electrooxidation and Ozone Treatment

In Figure 7 the TOC removal as a function of treatment time is shown, the removal is higher by using the electrooxidation treatment, and in the case of ozonation the removal is lower by 50 percent with respect to TOC.

Figure 7: Influence of the TOC removal in the electrooxidation () and ozonation treatment ().

In the first minutes, the results are similar in both methods because in the two methods hydroxyl radicals are available to attack the PHPH; however, the electrochemical treatment requires less steps to produce the radicals (since they are produced directly on the electrode surface), while the ozone requires more steps to produce the radicals and also is limited by the gas-liquid mass transfer phenomena.

3.5. Mechanism

The PHPH degradation mechanism is presented in Figure 8.

Figure 8: Proposed mechanism for the PHPH mineralization.

4. Conclusions

In this work we present two methods for the degradation of PHPH present in an aqueous solution. The electrochemical method requires acidic conditions to reach a 71% COD removal, whereas the ozone method requires basic conditions to obtain a 25% COD removal. This fact relies on the hydroxyl radicals production, which is faster in the electrochemical methods since less steps are required and a large anodic area provides a good mass transfer. The production of hydroxyl radicals using ozone involves more reactions and the mass transfer involves two phases: the gas and liquid.

Competing Interests

The authors declare that they have no competing interests.

Acknowledgments

The authors wish to acknowledge financial support from the CONACYT through the Project 153898, which is greatly appreciated.

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