Research Article
Synthesis, Characterization, and Catalytic Studies of Mn(III)-Schiff Base-Dicyanamide Complexes: Checking the Rhombicity Effect in Peroxidase Studies
Table 1
Crystal data and structure refinement for H2L2 and complex 1.
| | | H2L2 | Complex 1 |
| | Chemical formula | C20H24N2O4 | C24H20MnN5O5 | | Formula weight | 356.41 | 513.39 | | Crystal system | Triclinic | Triclinic | | Space group | | | | Temperature (K) | 100 | 100(2) | | (Å) | 8.3632(6) | 8.3157(4) | | (Å) | 10.5626(7) | 11.9711(6) | | (Å) | 11.4846(7) | 12.7633(10) | | (°) | 108.689(2) | 114.321(3) | | (°) | 95.176(2) | 102.633(3) | | (°) | 103.965(2) | 97.626(2) | | Volume (Å3) | 917.00(11) | 1093.74(11) | | 2 | 2 | | Radiation type | Mo Kα | Mo Kα | | (mm−1) | 0.09 | 0.653 | | Crystal size (mm) | 0.2 × 0.11 × 0.03 | 0.12 × 0.11 × 0.06 | | , | 0.942, 0.997 | 0.9619, 0.9858 | | 380 | 528 | | Number of measured reflections | 11933 | 20087 | | Number independent reflections | 3607 | 4293 | | Reflections observed | 2055 | 3209 | | 0.054 | 0.0374 | | (Å−1) | 0.617 | 0.0752 | | 0.049 | 0.0630 | | 0.128 | 0.0816 | | Number of parameters | 247 | 332 | | , (e Å−3) | 0.31, −0.28 | 0.338, −0.423 |
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