Synthesis, Characterization, and Catalytic Studies of Mn(III)-Schiff Base-Dicyanamide Complexes: Checking the Rhombicity Effect in Peroxidase Studies
Peroxidase activity for complexes 1–22, axial and equatorial crystal distances around the manganese ion for each complex with solved crystallographic structure, resulting tetragonal elongation, and corresponding reference.
Tetragonal elongation expressed as the ratio between the manganese-axial oxygen distances and the manganese-equatorial oxygen distances. Peroxidase activity expressed as percentage of conversion of ABTS to ABTS•+ measured 10 min after mixing the solutions; D = H2O or other solvent molecule (such as CH3OH); un.: unavailable (structure not solved).
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