Enthalpic Contribution of Ni(II) in the Interaction between Carbonaceous Material and Aqueous Solution

<div>Ion Ni(II) differential enthalpy change, <svg height="14.9882pt" id="M39" style="vertical-align:-6.352301pt" version="1.1" viewbox="-0.0498162 -8.6359 51.2095 14.9882" width="51.2095pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M600 0V24L339 665L311 657L43 24V0H600ZM497 50H107L303 539L497 50Z" id="g113-133"></path><glyph.data ascent="3473" descent="-2876" horiz-adv-x="641" vert-adv-y="641" xpluscharwidth="8.333"></glyph.data></g><g transform="matrix(.013,0,0,-0.013,8.327,0)"><path d="M828 650H570L564 622C646 614 650 609 634 524L604 366H253L281 524C296 608 308 615 382 622L388 650H132L126 622C211 615 214 609 198 524L121 122C106 42 102 35 23 28L17 0H276L282 28C196 35 191 40 206 122L243 324H597L559 123C544 42 537 35 452 28L446 0H710L716 28C632 35 628 43 643 122L719 524C735 610 741 615 822 622L828 650Z" id="g113-73"></path><glyph.data ascent="3473" descent="-2876" horiz-adv-x="840" vert-adv-y="840" xpluscharwidth="19.247"></glyph.data></g><g transform="matrix(.0091,0,0,-0.0091,19.325,3.132)"><path d="M43 650V617C122 612 130 606 130 522V128C130 44 122 37 34 32V0H275C400 0 497 25 573 82C652 142 698 229 698 350C698 445 662 518 613 565C549 625 456 650 327 650H43ZM217 544C217 580 220 591 229 599C240 607 264 613 311 613C380 613 437 599 482 570C561 523 598 436 598 336C598 177 511 40 324 40C248 40 217 61 217 135V544Z" id="g58-66"></path><glyph.data ascent="1007" descent="-369" horiz-adv-x="744" vert-adv-y="744" xpluscharwidth="26.09537768"></glyph.data></g><g transform="matrix(.0091,0,0,-0.0091,26.032,3.132)"><path d="M308 0V33C225 38 217 44 217 128V521C217 605 225 612 308 617V650H39V617C122 612 130 605 130 521V128C130 44 122 38 39 33V0H308Z" id="g58-71"></path><glyph.data ascent="1007" descent="-369" horiz-adv-x="348" vert-adv-y="348" xpluscharwidth="29.19878956"></glyph.data></g><g transform="matrix(.0091,0,0,-0.0091,29.198,3.132)"><path d="M502 500C497 551 492 613 491 650H43V617C122 612 130 606 130 521V129C130 45 122 38 41 33V0H319V33C227 38 217 45 217 129V305H319C411 305 413 295 427 225H461V421H427C414 357 411 348 319 348H217V580C217 609 219 612 250 612H330C401 612 423 605 439 578C452 557 458 539 467 496L502 500Z" id="g58-68"></path><glyph.data ascent="1007" descent="-369" horiz-adv-x="540" vert-adv-y="540" xpluscharwidth="34.1119838"></glyph.data></g><g transform="matrix(.0065,0,0,-0.0065,34.168,5.233)"><path d="M731 650H485V618C556 614 580 601 585 558C588 530 592 485 592 390V153H589L173 650H22V618C69 614 92 606 112 582C131 558 132 555 132 483V266C132 175 129 128 125 96C120 49 95 36 36 33V0H281V33C212 36 188 50 183 98C180 129 177 175 177 266V510H179L603 -9H638V390C638 483 640 530 644 561C649 602 674 615 731 618V650Z" id="g58-76"></path><glyph.data ascent="1007" descent="-369" horiz-adv-x="754" vert-adv-y="754" xpluscharwidth="39.069"></glyph.data></g><g transform="matrix(.0065,0,0,-0.0065,38.932,5.233)"><path d="M138 535C169 535 191 560 191 589C191 620 168 644 139 644S85 620 85 589C85 560 110 535 138 535ZM257 0V30C192 35 185 43 185 109V453C142 435 94 422 40 414V386C101 378 104 372 104 311V109C104 41 97 35 33 30V0H257Z" id="g58-103"></path><glyph.data ascent="1007" descent="-369" horiz-adv-x="275" vert-adv-y="275" xpluscharwidth="40.719500000000004"></glyph.data></g><g transform="matrix(.0065,0,0,-0.0065,40.72,5.233)"><path d="M318 -137C221 -59 159 100 159 272S220 600 318 680L294 710C146 612 80 452 80 273V272C80 91 146 -72 294 -168L318 -137Z" id="g176-41"></path><glyph.data ascent="3439" descent="-2858" horiz-adv-x="370" vert-adv-y="370" xpluscharwidth="43.125"></glyph.data></g><g transform="matrix(.0065,0,0,-0.0065,43.124,5.233)"><path d="M308 0V33C225 38 217 44 217 128V521C217 605 225 612 308 617V650H39V617C122 612 130 605 130 521V128C130 44 122 38 39 33V0H308Z" id="g58-71"></path><glyph.data ascent="1007" descent="-369" horiz-adv-x="348" vert-adv-y="348" xpluscharwidth="45.386"></glyph.data></g><g transform="matrix(.0065,0,0,-0.0065,45.386,5.233)"><path d="M308 0V33C225 38 217 44 217 128V521C217 605 225 612 308 617V650H39V617C122 612 130 605 130 521V128C130 44 122 38 39 33V0H308Z" id="g58-71"></path><glyph.data ascent="1007" descent="-369" horiz-adv-x="348" vert-adv-y="348" xpluscharwidth="47.648"></glyph.data></g><g transform="matrix(.0065,0,0,-0.0065,47.648,5.233)"><path d="M291 272C291 452 228 611 76 710L51 680C147 602 211 444 211 272S151 -55 51 -137L76 -168C227 -66 291 91 291 272Z" id="g176-42"></path><glyph.data ascent="3439" descent="-2858" horiz-adv-x="370" vert-adv-y="370" xpluscharwidth="50.053000000000004"></glyph.data></g></svg>, in function of the oxygen content groups on the carbonized surface. (a) Carboxylic groups content, (b) total acidity.</div>

Journal of Chemistry

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Figure 6

Figure 6: Enthalpic Contribution of Ni(II) in the Interaction between Carbonaceous Material and Aqueous Solution 