Research Article

Enhanced As (V) Removal from Aqueous Solution by Biochar Prepared from Iron-Impregnated Corn Straw

Table 4

Calculation of saturation indices (SI) for precipitation phases using the equilibrium concentrations in solution at the initial As (V) of 40 mg L−1 in the CS-Fe.

PhaseReactionlog KspSI

FeAsO42H2OFeAsO42H2O = Fe3+ + + 2H2O−20.2−3.525
AlAsO42H2OAlAsO42H2O = Al3+ + + 2H2O−15.8−9.275
Ca3(AsO4)24H2OCa3(AsO4)24H2O = 3Ca2+ + + 4H2O−18.9−33.105
Ca5(AsO4)3OHCa5(AsO4)3OH = 5Ca2+ + + OH−40.12−51.179
Ca4(OH)(AsO4)24H2OCa4(OH)(AsO4)24H2O = 4Ca2+ + + OH + 4H2O−27.49−51.098

Notes. Calculations performed using the Visual MINTEQ speciation model.