Review Article
Nanoparticles Used for Extraction of Polycyclic Aromatic Hydrocarbons
Table 11
Some magnetic and magnetised NPs used in the extraction of PAHs.
| Nanoparticles | No. of PAHs | Matrix | Extraction technique | Detection method | Amount of sorbent (mg) | Extraction time (min) | Recovery (%) | LOD | Ref. |
| MNP-FA | 4 | Leachate, sludge | MSPE | HPLC-DAD | 15 | 15 | 81.1–119.3 | 0.01–0.05 ng·mL−1 | [136] | Fe3O4-CTAB | 15 | Water | SPE | UPLC-FLD | 50 | 5 | 59.23–87.95 | 0.4–10.3 ng·mL−1 | [140] | Fe3O4-PDA | 6 | Water | SPE | HPLC | 20 | 5 | 76–107 | 0.51–1.92 ng·L−1 | [139] | Fe3O4/MWC/alginate composite | 3 | Water | MSPE | HPLC-FID | 200 | — | 92–97.7 | 0.005 ng·mL−1 | [130] | Fe3O4/CNS/ppy | 5 | Water | MSPE | GC-FID | 20 | 10 | 88.9–99 | 0.01–0.05 ng·mL−1 | [141] | Fe3O4@ppy-MWCN | 5 | Water, soil | MSPE | GCMS | 13 | 3 | 85.4–106.8 | 0.001–0.003 ng·mL−1 | [129] | Fe3O4/MWCN | 7 | Water | MSPE | UHHPLC | 5 | 5 | 76.4–106.5 | 0.025–0.73 ng·mL−1 | [128] | Fe3O4@SiO2-GO-PEA | 10 | Water | MSPE | GC-FID | 30 | 5 | 0.005–0.1 | 71.7–106.7 ng·mL−1 | [119] | Fe3O4@Agcore@ shell | 5 | Water | MSPE | HPLC-UV | 50 | 20 | 0.02–0.1 | 82.4–109 ng·mL−1 | [142] | COF-LZUI@PEI@ Fe3O4 | 6 | Water | MSPE | HPLC | 5 | 30 | 90.9–107.8 | 0.2–20 pg·mL−1 | [143] | 6 | Soil | MSPE | HPLC | 5 | 30 | 85.1–105 | Magnetic Au-NH2-MCM-4 | 5 | Seawater | DLLME | GC-FID | 30 | 5 | 91.4–104.2 | 0.002–0.004 µg·L−1 | [91] |
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